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5344-90-1 - 2-Aminobenzyl alcohol, 98% - 2-(Hydroxymethyl)aniline - A13180 - Alfa Aesar

A13180 2-Aminobenzyl alcohol, 98%

CAS 번호
5344-90-1
동의어
2-(Hydroxymethyl)aniline

사이즈 가격 ($) 수량 재고 여부
10g 27.20
50g 90.40
250g 399.00
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2-Aminobenzyl alcohol, 98%

MDL
MFCD00007749
EINECS
226-293-7

화학적 특성

화학식
C7H9NO
화학 식량
123.16
융점
81-84°
비등점
160°/10mm
용해도
Very soluble in water.

용도

2-Aminobenzyl alcohol is oxidatively cyclised with an array of ketones in dioxane at 80°C in the presence of a ruthenium catalyst and KOH to give corresponding quinolines. It undergoes oxidation catalyzed by heterotrimetallic RuMnMn species on the hydrotalcite surface in the presence of O2 to yield 2-aminobenzaldehyde. was used in the synthesis of ethyl 2-hydroxymethylcarbanilate.

참고

Store at room temperature. Incompatible with oxidizing agents.

참조 문헌

Chan Sik Cho.; Bok Tae Kim.; Tae-Jeong Kim.; Sang Chul Shim. Ruthenium-catalysed oxidative cyclisation of 2-aminobenzyl alcohol with ketones: modified Friedlaender quinoline synthesis.Chem. Commun. 2001, (24),2576-2577 .

Chan Sik Cho.; Bok Tae Kim.; Heung-Jin Choi.; Tae-Jeong Kim.; Sang Chul Shim. Ruthenium-catalyzed oxidative coupling and cyclization between 2-aminobenzyl alcohol and secondary alcohols leading to quinolines. Tetrahedron. 2003, 59 (40),7997-8002 .

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
1072211
통합 관세 코드
2922.19
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
DN3155000

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