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770-09-2 - Benzyltrimethylsilane, 98% - A13191 - Alfa Aesar

A13191 Benzyltrimethylsilane, 98%

CAS 번호
770-09-2
동의어

사이즈 가격 ($) 수량 재고 여부
25g 88.90
100g 299.00
장바구니에 추가 대량 견적에 추가 항목 보기

Benzyltrimethylsilane, 98%

MDL
MFCD00039796
EINECS
212-218-5

화학적 특성

화학식
C6H5CH2Si(CH3)3
화학 식량
164.32
비등점
190-191°
인화점
57°(134°F)
밀도
0.866
굴절률
1.4940
용해도
Insoluble in water.

용도

Benzyltrimethylsilane is a silicon reagent for generating benzyl anions.

참고

Store at room temperature. Incompatible with oxidizing agents.

참조 문헌

Shunichi Fukuzumi.; Naoya Satoh.; Toshihiko Okamoto.; Kiyomi Yasui.; Tomoyoshi Suenobu .; Yasuyo Seko.; Mamoru Fujitsuka.; Osamu Ito. Change in Spin State and Enhancement of Redox Reactivity of Photoexcited States of Aromatic Carbonyl Compounds by Complexation with Metal Ion Salts Acting as Lewis Acids. Lewis Acid-Catalyzed Photoaddition of Benzyltrimethylsilane and Tetramethyltin via Photoinduced Electron Transfer. J. Am. Chem. Soc. 2001, 123 (32),7756-7766 .

Hiroshi Hiratsuka.; Yukihiro Kadokura.; Hiroyuki Chida.; Miéko Tanaka.; Satoshi Kobayashi.; Tetsuo Okutsu.; Makoto Oba.; Kozaburo Nishiyama. Photochemical processes of benzyltrimethylsilane at 77 K remarkable solvent effects and reaction mechanism.J. Chem. Soc., Faraday Trans. 1996, 92 (17),3035-3041 .

Peterson olefination reaction of the lithio-derivative with aromatic aldehydes gives mixtures of (E)- and (Z)-stilbenes: J. Org. Chem., 33, 780 (1968). See Appendix 4.

In the presence of F-, acts as a benzyl carbanion equivalent: Bull. Soc. Chim. Fr. II, 90 (1985):

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H226

Flammable liquid and vapour.

주의 설명서: P210-P280a-P240-P241-P303+P361+P353-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
1928113
위험 등급
3
포장 그룹
III
통합 관세 코드
2931.90
TSCA(독성물질규제법)"
Yes

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