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100-39-0 - Benzyl bromide, 99% - alpha-Bromotoluene - A13535 - Alfa Aesar

A13535 Benzyl bromide, 99%

CAS 번호
100-39-0
동의어
alpha-Bromotoluene

사이즈 가격 ($) 수량 재고 여부
50g 23.90
250g 91.10
1000g 285.00
장바구니에 추가 대량 견적에 추가 항목 보기

Benzyl bromide, 99%

MDL
MFCD00000172
EINECS
202-847-3

화학적 특성

화학식
C7H7Br
화학 식량
171.04
융점
-4°
비등점
198-199°
인화점
87°(189°F)
밀도
1.438
굴절률
1.5750
감도
Moisture Sensitive
용해도
Miscible with benzene, carbon tetrachloride, ethanol and ether.

용도

Benzyl bromide is widely useful in organic synthesis as a benzyl protecting group for alcohols and carboxylic acids. It is used in the preparation of foaming and frothing agents, quaternary ammonium compounds, peniclins, photographic chemicals, synthetic resins, dyes and plasticizers and esters. It is also involved in the synthesis of (E)-(2-Iodovinyl)benzene by reacting it with diiodomethane.

참고

Light and moisture sensitive. Incompatible with bases, alcohols, amines, oxidizing agents and corrodes steel.

참조 문헌

Si, W.; Zhang, X.; Asao, N.; Yamamoto, Y.; Jin, T. Ni-Catalyzed direct 1,4-difunctionalization of [60]fullerene with benzyl bromides. Chem. Commun. 2015, 51 (29), 6392-6394.

Behera, A.; Ali, W.; Guin, S.; Khatun, N.; Mohanta, P. R.; Patel, B. K. Benzyl bromides as aroyl surrogates in substrate directed Pd catalysed o-aroylation. RSC Adv. 2015, 5 (42), 33334-33338.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H227-H314-H319-H335

Combustible liquid. Causes severe skin burns and eye damage. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P280-P305+P351+P338-P309-P310a

Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: Immediately call a POISON CENTER/doctor

기타 참조

Merck
14,1128
바일슈타인
385801
위험 등급
6.1
포장 그룹
II
통합 관세 코드
2903.99
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
XS7965000

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