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75-47-8 - Iodoform, 99% - Triiodomethane - A13664 - Alfa Aesar

A13664 Iodoform, 99%

CAS 번호
75-47-8
동의어
Triiodomethane

사이즈 가격 ($) 수량 재고 여부
50g 27.20
250g 97.50
1000g 363.00
장바구니에 추가 대량 견적에 추가 항목 보기

Iodoform, 99%

MDL
MFCD00001069
EINECS
200-874-5

화학적 특성

화학식
CHI3
화학 식량
393.73
융점
118-123°
인화점
None
밀도
4.008
감도
Light Sensitive
용해도
Soluble in water, ether, acetic acid, ethanol, chloroform, ether, glycerol, carbon disulfide, olive oil, benzene and acetone. Slightly soluble in petroleum ether.

용도

Iodoform is use as a disinfectant. It is an active ingredient of ear powder along with other constituents like zinc oxide and propanoic acid, which prevent infection and facilitate the removal of ear hair in dogs and cats. In analytical chemistry, it is involved in the determination of iodoform in drinking water as well as to remove heavy metals like mercury from fluids. It plays an important role in the fermentation of bio mass. It is also used in root canal therapy for infected primary teeth.

참고

Light sensitive. Incompatible with strong bases, alkali metals, trong oxidizing agents and magnesium.

참조 문헌

Precursor of diiodocarbene under phase-transfer conditions: Angew. Chem. Int. Ed., 13, 132 (1974), or using KO-t-Bu: Synthesis, 313 (1976). Generation of diiodocarbene with NaH in ether and reaction with malonate is the first step of a route to vinyl iodides: J. Chem. Soc., Perkin 1, 47 (1990):

In the presence of solid NaOH, free radical iodination of saturated hydrocarbons has been accomplished under mild conditions. The reaction is thought to involve the triiodomethyl radical as a chain carrier: Angew. Chem. Int. Ed., 38, 2786 (1999).

Gu, J.; Yan, X.; Fu, Z.; Yang, W.; Shi, Y. Iodoform-mediated free radical emulsion polymerization of chloroprene. J. Appl. Polym. Sci 2013, 128 (4), 2291-2296.

Zall, A.; Bensinger, D.; Schmidt, B. Oxidative Homologation of Aldehydes to α-Ketoaldehydes by using Iodoform, o-Iodoxybenzoic Acid, and Dimethyl Sulfoxide. Eur. J. Org. Chem. 2012, 2012 (7), 1439-1447.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H302-H312-H332-H315-H319-H335

Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P261-P280-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

Merck
14,5033
바일슈타인
1697010
통합 관세 코드
2903.39
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
PB7000000

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