Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

20605-01-0 - Diethyl bis(hydroxymethyl)malonate, 97% - Bis(hydroxymethyl)malonic acid diethyl ester - A13677 - Alfa Aesar

A13677 Diethyl bis(hydroxymethyl)malonate, 97%

CAS 번호
20605-01-0
동의어
Bis(hydroxymethyl)malonic acid diethyl ester

사이즈 가격 ($) 수량 재고 여부
25g 52.90
100g 132.00
500g 505.00
장바구니에 추가 대량 견적에 추가 항목 보기

Diethyl bis(hydroxymethyl)malonate, 97%

MDL
MFCD00009130
EINECS
243-916-8

화학적 특성

화학식
C9H16O6
화학 식량
220.22
융점
47-52°
인화점
>110°(230°F)
용해도
Slightly soluble in water.

용도

Diethyl bis(hydroxymethyl)malonate is used as a reagent for preparing 1,3-dioxanes from acetals, aldehydes and ketones. It is also used as an intermediate for the preparation of substituted malonic, acrylic and isobutyric esters, for conversion to the useful dienophiles, ?-bromomethylacrylic acid and its ethyl ester and to bis(bromomethyl)acetic acid and its methyl ester.

참고

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

참조 문헌

Ross A. Miller.; Fengrui Lang.; Benjamin Marcune.; Daniel Zewge.; Zhiguo J. Song.; Sandor Karady. A Practical Process for the Preparation of Azetidine-3-carboxylic Acid. Synthetic Communications: An International Journal for Rapid Communication of Synthetic Organic Chemistry. 2003, 33 (19), 3347-3353.

Shiyue Fang.; Donald E. Bergstrom. Reversible Biotinylation Phosphoramidite for 5‘-End-Labeling, Phosphorylation, and Affinity Purification of Synthetic Oligonucleotides. Bioconjugate Chem. 2003, 14 (1), 80-85.

Intermediate for the preparation of substituted malonic, acrylic and isobutyric esters: J. Chem. Soc., 257 (1930); J. Org. Chem., 20, 780 (1955). For conversion to the useful dienophiles, ɑ-bromomethylacrylic acid and its ethyl ester, see: Org. Synth. Coll., 7, 210 (1990), and to bis(bromomethyl)acetic acid and its methyl ester, Org. Synth. Coll., 7, 319 (1990).

기타 참조

바일슈타인
1788515
통합 관세 코드
2918.19
TSCA(독성물질규제법)"
Yes

권장

최근에 본 것

화학물질

화학물질

금속 및 재료

촉매

분석 기기 및 실험실 용품