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76-86-8 - Chlorotriphenylsilane, 96% - Triphenylchlorosilane - TPSCl - A13678 - Alfa Aesar

A13678 Chlorotriphenylsilane, 96%

CAS 번호
76-86-8
동의어
Triphenylchlorosilane
TPSCl

사이즈 가격 ($) 수량 재고 여부
5g 19.30
25g 68.60
50g 129.00
100g 233.00
장바구니에 추가 대량 견적에 추가 항목 보기

Chlorotriphenylsilane, 96%

MDL
MFCD00000496
EINECS
200-989-0

화학적 특성

화학식
C18H15ClSi
화학 식량
294.86
융점
91-96°
비등점
188-189°/3mm
인화점
>200°(392°F)
감도
Moisture Sensitive
용해도
Reacts with water.

용도

Chlorotriphenylsilane is used as a silylating agent. It is also used as a pharmaceutical intermediate.

참고

Keep container tightly sealed. Store under dry inert gas. It is sensitive to moisture. Incompatible with bases and oxidizing agents.

참조 문헌

Raymond C. Petersen.; Sidney D. Ross. Displacement Reactions on Silicon. The Reaction of 2-Propanol with Chlorotriphenylsilane in Carbon Tetrachloride. J. Am. Chem. Soc. 1963, 85 (20), 3164-3167.

Henry Gilman.; Glen D. Lichtenwalter. Cleavage of Symmetrically Substituted Disilanes by Lithium in Tetrahydrofuran. J. Am. Chem. Soc. 1958, 80 (3), 608-611.

Silylating agent: J. Chem. Soc., 3403 (1963); see Appendix 4. The stability of the bulky triphenylsilyl (TPS) ethers to basic hydrolysis is similar to TMS, but they are about 400x more stable to acid hydrolysis. Suitable conditions for their cleavage include: ethanolic NaOH; AcOH - water - THF at 70o: Chem. Lett., 1499 (1979); and TBAF: J. Am .Chem. Soc., 108, 3827 (1986).

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

주의 설명서: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
1820487
위험 등급
8
포장 그룹
II
통합 관세 코드
2931.90
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
VV2720000

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