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16903-61-0 - Bis(triphenylphosphine)copper(I) borohydride - Bis(triphenylphosphine)copper(I) tetrahydridoborate - Tetrahydridoboratobis(triphenylphosphine)copper(I) - A13730 - Alfa Aesar

A13730 Bis(triphenylphosphine)copper(I) borohydride

CAS 번호
16903-61-0
동의어
Bis(triphenylphosphine)copper(I) tetrahydridoborate
Tetrahydridoboratobis(triphenylphosphine)copper(I)

사이즈 가격 ($) 수량 재고 여부
5g 26.00
25g 87.80
100g 245.00
장바구니에 추가 대량 견적에 추가 항목 보기

Bis(triphenylphosphine)copper(I) borohydride

MDL
MFCD00013219
EINECS
240-951-0

화학적 특성

화학식
C36H34BCuP2
화학 식량
602.97
융점
ca 175° dec.
감도
Moisture Sensitive

참조 문헌

Specific reagent for reduction of acid chlorides to aldehydes: Tetrahedron Lett., 1437 (1978); 975 (1979). Also reduces sulfonylhydrazones to alkanes: Tetrahedron Lett., 4031 (1980), and aryl azides to amines: J. Chem. Res. (Synop.), 17 (1981).

/n

In the presence of Lewis acids or HCl, reduces carbonyl compounds with good stereo- and chemo-selectivity, e.g. aldehydes in the presence of ketones: Tetrahedron Lett., 22, 675 (1981).

/n

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H261-H315-H319-H335

In contact with water releases flammable gas. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P231+P232-P261-P280a-P305+P351+P338-P405-P501a

Handle under inert gas. Protect from moisture. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

위험 등급
4.3
포장 그룹
III
통합 관세 코드
2931.39
TSCA(독성물질규제법)"
No

권장

최근에 본 것

화학물질

화학물질

금속 및 재료

촉매

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