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6485-40-1 - (R)-(-)-Carvone, 98% - (R)-(-)-5-Isopropenyl-2-methyl-2-cyclohexenone - (R)-(-)-p-Mentha-6,8-dien-2-one - A13900 - Alfa Aesar

A13900 (R)-(-)-Carvone, 98%

CAS 번호
6485-40-1
동의어
(R)-(-)-5-Isopropenyl-2-methyl-2-cyclohexenone
(R)-(-)-p-Mentha-6,8-dien-2-one

사이즈 가격 ($) 수량 재고 여부
50g 25.20
250g 92.50
1000g 307.00
장바구니에 추가 대량 견적에 추가 항목 보기

(R)-(-)-Carvone, 98%

MDL
MFCD00001578
EINECS
229-352-5

화학적 특성

화학식
C10H14O
화학 식량
150.22
비등점
228-230°
인화점
93°(199°F)
밀도
0.959
굴절률
1.4990
용해도
Miscible with alcohol, ether, chloroform, propylene glycol and mineral oils. Immiscible with water and glycerol.

용도

(R)-(-)-Carvone is used in the flavor and food industry such as chewing gum additives. It is used in air freshening products such as in essential oils as well as in aromatherapy and alternative medicine. It is used to prepare carvomenthol, carvomenthone, dihydrocarvone, carveol and limonene. It reacts with lithium dimethylcuprate to place a methyl group trans to the isopropenyl group with good stereoselectivity. It is also used as a mosquito repellent and prevent premature sprouting of potatoes. Further, it is employed as an important starting material for the synthesis of enantiopure (R)-(+)-3-methyl-6-isopropenyl-cyclohept-3-enone-1 and (4S,6R,7R)-trihydroxy-1-octyne derivatives. It is utilized as a vital raw material for the asymmetric total synthesis of natural products. In addition to this, it is used as a chiral starting material.

참고

Store in a cool place. Incompatible with strong oxidizing agents.

참조 문헌

Kumaran, R. S.; Mehta, G. An enantiodivergent protocol from R-(-)-carvone: synthesis of dihydroagarofuran sesquiterpenoid 1-deacetoxy-ent-orbiculin A. Tetrahedron 2015, 71 (10), 1547-1554.

Perna, J. C.; Wotjak, C. T.; Stork, O.; Engelmann, M. Timing of presentation and nature of stimuli determine retroactive interference with social recognition memory in mice. Physiol. Behav. 2015, 143, 10-14.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H227-H302

Combustible liquid. Harmful if swallowed.

주의 설명서: P280f

Wear protective clothing.

기타 참조

바일슈타인
2206714
통합 관세 코드
2914.29
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
OS8650000

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