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591-31-1 - 3-Methoxybenzaldehyde, 98% - m-Anisaldehyde - A13962 - Alfa Aesar

A13962 3-Methoxybenzaldehyde, 98%

CAS 번호
591-31-1
동의어
m-Anisaldehyde

사이즈 가격 ($) 수량 재고 여부
25g 31.70
100g 97.10
500g 330.00
장바구니에 추가 대량 견적에 추가 항목 보기

3-Methoxybenzaldehyde, 98%

MDL
MFCD00003361
EINECS
209-712-8

화학적 특성

화학식
C8H8O2
화학 식량
136.15
비등점
231-233°
인화점
121°(250°F)
밀도
1.118
굴절률
1.5530
감도
Air Sensitive
용해도
Slightly soluble in water. Soluble in glacial acetic acid, alcohol, chloroform, ether, carbon disulfide, methanol, aqueous solutions of alkali hydroxides.

용도

3-Methoxybenzaldehyde is used to prepare 3-(3-methoxy-phenyl)-1-phenyl-propenone by reaction with benzldehyde. It is used as an eluent for mono-13C isotopomers of vanillin in normal phase silica gel chromatography. It acts as an inhibitor of 4-(methylnitrosamino)-1-(3-pyridyl)-1-butanone (NNK) metabolism.

참고

Air sensitive. Incompatible with strong bases, strong oxidizing agents and strong reducing agents.

참조 문헌

Lithiation and methylation normally gives a mixture of 2-, 4- and 6-methyl derivatives. Systematic study has found that using PhLi and trimethylethylenediamine increases the degree of 2-lithiation to 96%: J. Org. Chem., 54, 3730 (1989).

Bhowmick, D.; Srivastava, S.; D’Silva, P.; Mugesh, G. Highly Efficient Glutathione Peroxidase and Peroxiredoxin Mimetics Protect Mammalian Cells against Oxidative Damage. Angew. Chem. 2015, 127 (29), 8569-8573.

Marri, G.; Reddy, J. S.; Ruiz, J.; Das, S.; Gree, R. Stereoselective TiCl4-Mediated Aldol Reactions Starting from Acylsilanes. Eur. J. Org. Chem. 2015, 2015 (4), 840-846.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H315-H319

Causes skin irritation. Causes serious eye irritation.

주의 설명서: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

기타 참조

바일슈타인
606013
통합 관세 코드
2912.49
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
BZ2605000

권장

최근에 본 것

화학물질

화학물질

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