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A13979 Diphenylacetylene, 99%

CAS 번호
501-65-5
동의어
Tolan

Stock No. 사이즈 가격 ($) 수량 재고 여부
A13979-06 5g 22.20
A13979-14 25g 49.50
A13979-22 100g 173.00
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Diphenylacetylene, 99%

MDL
MFCD00004786
EINECS
207-926-6

화학적 특성

화학식
C14H10
화학 식량
178.23
융점
58-62°
비등점
170°/19mm
밀도
0.990
Storage & Sensitivity
Keep Cold.
용해도
Miscible with ether and hot alcohol. Immiscible with water.

용도

Diphenylacetylene is often used as a building block in organic and organometallic chemistry. It acts as dienophile and under goes Diels-Alder reaction with tetraphenylcyclopentadienone to prepare hexaphenylbenzene. It acts as a precursor in the preparation of 3-alkoxycyclopropene by reacting with benzal chloride in the presence of potassium t-butoxide.

참고

Incompatible with strong oxidizing agents.

참조 문헌

For an example of use as a Diels-Alder dienophile, see: Org. Synth. Coll., 5, 604 (1973).

For transfer of methylene groups from dimsyl sodium, giving 2,3-diphenylbutadiene, see: Org. Synth. Coll., 6, 531 (1988).

Can be oxidized to benzil using iodine-DMSO: Synthesis, 131 (1991).

Shi, Y.; Li, G.; Zhao, B.; Chen, Y.; Chao, P.; Zhang, H.; Wang, X.; Wang, T. Synthesis and optical properties of cationic cyclopentadienyl iron complexes with diphenylacetylene chromophores. Inorg. Chim. Acta 2015, 427, 259-265.

Le, K. V.; Aya, S.; Ogino, S.; Okano, K.; Araoka, F.; Takezoe, H. Large Twist Elastic Constant in Diphenylacetylene-Core-Based Liquid Crystals. Mol Cryst Liq Cryst 2015, 614 (1), 124-127.

기타 참조

Merck
14,9504
바일슈타인
606478
통합 관세 코드
2902.90
TSCA(독성물질규제법)"
Yes

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