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1100-88-5 - Benzyltriphenylphosphonium chloride, 99% - A14034 - Alfa Aesar

A14034 Benzyltriphenylphosphonium chloride, 99%

CAS 번호
1100-88-5
동의어

사이즈 가격 ($) 수량 재고 여부
25g 0.00
100g 61.40
500g 274.00
장바구니에 추가 대량 견적에 추가 항목 보기

Benzyltriphenylphosphonium chloride, 99%

MDL
MFCD00011913
EINECS
214-154-3

화학적 특성

화학식
C6H5CH2P(C6H5)3Cl
화학 식량
388.88
융점
ca 330° dec.
인화점
>300°(572°F)
감도
Hygroscopic
용해도
Soluble in water and alcohol. Insoluble in acetone.

용도

Benzyltriphenylphosphonium chloride is used as the accelerator of the Bisphenol AF curing system for fluoroelastomer. Also used as phase-transfer catalysts in the synthesis of certain organic compounds. It is used as a reactant for the synthesis of chemical compounds.

참고

Hygroscopic. Store under inert gas. Store away from strong oxidizing agents, water/ moisture..

참조 문헌

James McNulty; David McLeod. Amine- and sulfonamide-promoted Wittig olefination reactions in water. Chemistry: A European Journal. 2011, 17 (32), 8794-8798.

G.I Mukhayer; S.S Davis. Interactions between large organic ions of opposite charge: VI. Coacervation in mixtures of sodium dodecyl sulfate and benzyltriphenylphosphonium chloride. Journal of Colloid and Interface Science. 1978, 66 (1), 110-117.

Wittig olefination with carbonyl compounds can be carried out under basic, 2-phase conditions; the phosphonium salt acts as its own phase-transfer catalyst: Synthesis, 295 (1973). See also Appendix 1.

Benzylidene triphenylphosphoranes (formed with n-BuLi) are coupled by reaction with sulfur to give stilbenes, with elimination of triphenylphosphine sulfide: Chem. Ber., 103, 2995 (1970).

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H300-H315-H319-H335

Fatal if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P280h-P305+P351+P338-P309-P310a

Wear protective gloves/clothing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: Immediately call a POISON CENTER/doctor

기타 참조

바일슈타인
3599868
위험 등급
6.1
포장 그룹
II
통합 관세 코드
2931.39
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
TA2416500

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