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491-35-0 - Lepidine, 97% - 4-Methylquinoline - A14040 - Alfa Aesar

A14040 Lepidine, 97%

CAS 번호
491-35-0
동의어
4-Methylquinoline

사이즈 가격 ($) 수량 재고 여부
10g 42.40
50g 154.00
250g 674.00
장바구니에 추가 대량 견적에 추가 항목 보기

Lepidine, 97%

MDL
MFCD00006784
EINECS
207-734-2

화학적 특성

화학식
C10H9N
화학 식량
143.19
융점
9-10°
비등점
260-263°
인화점
>110°(230°F)
밀도
1.083
굴절률
1.6200
감도
Light Sensitive
용해도
Slightly soluble in water.

용도

Lepidine is used in the preparation of certain dyes.

참고

Light sensitive. Incompatible with oxidizing agents. Incompatible with oxidizing agents.

참조 문헌

K.R.Justin Thomas; Marappan Velusamy; Jiann T.Lin ; Chin-Hsiung Chien; Yu-Tai Tao; Yuh S.Wen; Ya-Hui Hu; Pi-Tai Chou. Efficient red-emitting cyclometalated iridium(III) complexes containing lepidine-based ligands. Inorg. Chem. 2005, 44,(16), 5677-5685

 

Martin J.Weiss; Charles R.Hauser. The acylation and carbethoxylation of quinaldine, lepidine and α-picoline using sodium amide or potassium amide. J. Am. Chem. Soc. 1949, 71,(6), 2023-2026.

Lepidine and similar compounds can be alkylated at the 2-position by free radicals generated by the action of t-butyl hydroperoxide and a salt of Fe(II) on a primary or secondary alkyl iodide: Acta Chem. Scand., 43, 995 (1989). Similarly, 2-formylation can be achieved in high yield using 1,3,5-trioxane in the presence of TFA, t-BuOOH and FeSO4 in acetonitrile: J. Org. Chem., 51, 536 (1986).

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H315-H319-H341

Causes skin irritation. Causes serious eye irritation. Suspected of causing genetic defects.

주의 설명서: P201-P280-P305+P351+P338-P308+P313-P405-P501a

Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

Merck
14,5441
바일슈타인
110926
통합 관세 코드
2933.49
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
OH0316000

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