Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

6138-90-5 - Geranyl bromide, 96% - 3,7-Dimethyl-2,6-octadienyl bromide - A14093 - Alfa Aesar

A14093 Geranyl bromide, 96%

CAS 번호
6138-90-5
동의어
3,7-Dimethyl-2,6-octadienyl bromide

사이즈 가격 ($) 수량 재고 여부
5g 44.40
25g 142.00
100g 456.00
장바구니에 추가 대량 견적에 추가 항목 보기

Geranyl bromide, 96%

MDL
MFCD00000243
EINECS
228-123-7

화학적 특성

화학식
C10H17Br
화학 식량
217.16
비등점
99-101°/10mm
인화점
95°(203°F)
밀도
1.094
굴절률
1.5040
감도
Light Sensitive
용해도
Immiscible with water.

용도

Geranyl bromide is used for the preparation of 3,7-dihydroxyflavone derivatives and baicalein. It is also involved in the synthesis of potential flavonoidic modulators of P-glycoprotein activity. Further, it reacts with benzenesulfinic acid to prepare geranyl phenyl sulfone. In addition to this, it takes part in the palladium catalyzed cross coupling with aryl and alkenylgold(I) phosphanes.

참고

Store in a cool place. Incompatible with strong oxidizing agents.

참조 문헌

Terpene building block.

The Horner reaction with Methyl­diphenyl­phosphine oxide, A11484, provides a convenient access to the natural product (3Z,6E)-ɑ-farnesene, greatly superior to earlier multistep approaches: J. Org. Chem., 60, 6211 (1995):

Schmidt, J.; Adrian, J.; Stark, C. B. W. Short and highly efficient synthesis of lipid peroxidation inhibitor pyrrolostatin and some analogues thereof. Org. Biomol. Chem. 2015, 13 (30), 8173-8176.

Xu, L.; Liu, Z.; Dong, W.; Song, J.; Miao, M.; Xu, J.; Ren, H. Copper-free arylation of 3,3-disubstituted allylic halides with triazene-softened aryl Grignard reagents. Org. Biomol. Chem. 2015, 13 (22), 6333-6337.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H227-H315-H318-H335

Combustible liquid. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation.

주의 설명서: P210u-P261-P280a-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
1422412
통합 관세 코드
2903.39
TSCA(독성물질규제법)"
Yes

권장

최근에 본 것

화학물질

화학물질

금속 및 재료

촉매

분석 기기 및 실험실 용품