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A14189 1,3-Dihydroxyacetone dimer, 97%

CAS 번호
62147-49-3
동의어
2,5-Dihydroxy-1,4-dioxane-2,5-dimethanol

Stock No. 사이즈 가격 ($) 수량 재고 여부
A14189-18 50g 20.40
A14189-30 250g 74.70
A14189-0B 1000g 265.00
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1,3-Dihydroxyacetone dimer, 97%

MDL
MFCD00051019
EINECS
612-947-2

화학적 특성

화학식
C6H12O6
화학 식량
180.16
융점
ca 75-82°
Storage & Sensitivity
Keep Cold. Hygroscopic. Store under Nitrogen.
용해도
Soluble in ethanol, ethyl ether, acetone. Slightly soluble in water. Insoluble in ligroin.

용도

1,3-Dihydroxyacetone dimer is used as a catalytic agent and petrochemical additive. It is also used as a building block in organic synthesis. Further, it serves as a reagent in three-carbon nucleophilic or electrophilic component in various reactions.

참고

Hygroscopic. Store in a cool place. Incompatible with strong oxidizing agents.

참조 문헌

In solid state, exists predominantly as trans-2,5-dihydroxy-1,4-dioxane-2,5-dimethanol (structure and CAS registry number as shown). On melting or in solution, mainly dissociates to monomeric 1,3-dihydroxyacetone [96-26-4]: J. Mol. Struct., 35, 85 (1976).

For a review of the dihydroxyacetone unit as a verstaile 3-carbon building block in organic synthesis, see: Angew. Chem. Int. Ed., 44, 1305 (2005).

Huang, Y.; Pathirana, C.; Ye, Q.; Palaniswamy, V. Non-enzymatic transformation of DL-glyceraldehyde, 1,3-dihydroxyacetone, and pyruvaldehyde with primary amine to the same DL-alanine derivatives. Tetrahedron Lett. 2015, 56 (30), 4516-4519.

Li, Y.; Zaera, F. Factors affecting activity and selectivity in the oxidation of glycerol promoted by platinum catalysts. Catal. Sci. Technol. 2015, 5 (7), 3773-3781.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

Merck
14,3182
바일슈타인
112910
통합 관세 코드
2932.99
TSCA(독성물질규제법)"
No

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