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756-79-6 - Dimethyl methylphosphonate, 97% - DMMP - Methylphosphonic acid dimethyl ester - A14268 - Alfa Aesar

A14268 Dimethyl methylphosphonate, 97%

CAS 번호
756-79-6
동의어
DMMP
Methylphosphonic acid dimethyl ester

사이즈 가격 ($) 수량 재고 여부
10g 17.00
100g 20.60
500g 87.10
장바구니에 추가 대량 견적에 추가 항목 보기

Dimethyl methylphosphonate, 97%

MDL
MFCD00008349
EINECS
212-052-3

화학적 특성

화학식
C3H9O3P
화학 식량
124.08
비등점
180-181°
인화점
68°(154°F)
밀도
1.16
굴절률
1.4130
용해도
Miscible with water, ethanol, ether, alcohol, benzene, acetone and carbon tetrachloride. Immiscible with heavy mineral oil.

용도

Dimethyl methylphosphonate is used as a catalyst and a reagent in organic synthesis for the conversion of esters to ketophosphonates. It is an additive for the synthesis of unsaturated polyester resin which has flame retardant high phosphorous and UV-cured epoxy acrylate. It finds application as hydraulic fluids as well.

참고

Incompatible materials strong oxidizing agents and strong bases.

참조 문헌

The lithio-derivative reacts with esters to give ß-ketophosphonates, useful precursors of ɑß-unsaturated ketones by Horner-Wadsworth-Emmons olefination: J. Am. Chem. Soc., 88, 5654 (1966). An intramolecular version leads to cyclopentenones: Synth. Commun., 5, 1 (1975); Tetrahedron Lett., 22, 257 (1981). Dimethyl glutarate gives the 3-(phosphonatomethyl)cyclohexenone, olefination of which affords the corresponding 3-alkenylcycloalkenone. Dimethyl succinate also gives this reaction, but in lower yield; higher diesters give acyclic products: J. Org. Chem., 59, 1943 (1994):

See also Diethyl­ methyl­phosphonate, A14772 and Appendix 1.

Park, E. J.; Han, S. W.; Jeong, B.; Park, S. H.; Kim, Y. G.; Kim, Y. H.; Kim, Y. D. Effect of polydimethylsiloxane (PDMS) coating on TiO2-based MALDI matrix for dimethyl methylphosphonate (DMMP) analysis. Appl. Surf. Sci. 2015, 353, 342-349.

Yoo, R.; Cho, S.; Song, M. J.; Lee, W. Highly sensitive gas sensor based on Al-doped ZnO nanoparticles for detection of dimethyl methylphosphonate as a chemical warfare agent simulant. Sens. Actuators, B 2015, 221, 217-223.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H227-H319-H340-H361

Combustible liquid. Causes serious eye irritation. May cause genetic defects. Suspected of damaging fertility or the unborn child.

주의 설명서: P210u-P201-P280-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

Merck
14,3391
바일슈타인
878263
통합 관세 코드
2931.31
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
SZ9120000

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