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700-58-3 - 2-Adamantanone, 98% - A14275 - Alfa Aesar

A14275 2-Adamantanone, 98%

CAS 번호
700-58-3
동의어

사이즈 가격 ($) 수량 재고 여부
5g 41.00
25g 132.00
100g 404.00
장바구니에 추가 대량 견적에 추가 항목 보기

2-Adamantanone, 98%

MDL
MFCD00074737
EINECS
211-847-2

화학적 특성

화학식
C10H14O
화학 식량
150.22
융점
ca 257° subl.
용해도
Solubility in methanol is almost transparent.

용도

It is used in the synthesis of dispiro N-Boc-protected 1,2,4-trioxane1 and (+/-)-1-(adamantan-2-yl)-2-propanamine. It is employed in reductive coupling (TiCl3/Li) which gives (adamantylidene)adamantane, an example of a general method for the synthesis of highly-substituted alkenes and in the preparation of highly-substituted alkenes by the Wittig reaction which gives poor yields with adamantanone.

참고

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

참조 문헌

Sunil Sabbani, et al. Piperidine dispiro-1,2,4-trioxane analogues.Bioorg Med Chem Lett.,2008,18(21), 5804-5808.

E Mariani, et al. (+/-)-1-(Adamantan-2-yl)-2-propanamine and other amines derived from 2-adamantanone.Farmaco Sci.,1980,35(5), 430-40.

Matthew M Meyer and Steven R Kass.Enolates in 3-D: an experimental and computational study of deprotonated 2-adamantanone.J Org Chem.,2010,75(12), 4274-4279.

Reductive coupling (TiCl3/Li) gives (adamantylidene)adamantane, an example of a general method for the synthesis of highly-substituted alkenes: Org. Synth. Coll., 7, 1 (1990).

Preparation of highly-substituted alkenes by the Wittig reaction gives poor yields with adamantanone. The route involving addition of a Grignard or alkyllithium reagent is to be preferred: J. Org. Chem., 54, 1375 (1989).

기타 참조

바일슈타인
1210235
통합 관세 코드
2914.29
TSCA(독성물질규제법)"
No
RTECS(화학물질 독성 등록)
AU5018000

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화학물질

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