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107-05-1 - Allyl chloride, 98%, stab. with propylene oxide - 3-Chloro-1-propene - A14330 - Alfa Aesar

A14330 Allyl chloride, 98%, stab. with propylene oxide

CAS 번호
107-05-1
동의어
3-Chloro-1-propene

사이즈 가격 ($) 수량 재고 여부
100ml 24.30
500ml 39.20
장바구니에 추가 대량 견적에 추가 항목 보기

Allyl chloride, 98%, stab. with propylene oxide

MDL
MFCD00000984
EINECS
203-457-6

화학적 특성

화학식
C3H5Cl
화학 식량
76.53
융점
-135°
비등점
44-46°
인화점
-28°(-18°F)
밀도
0.939
굴절률
1.4155
용해도
Soluble in water (3600 mg/L at 20°C), ethanol, ether, petroleum, acetone, chloroform, benzene, methanol and 2-prop.

용도

Allyl chloride is used as an alkylating agent. It is used in treatment with sodium bis(trimethylsilyl)amide gives the strained, highly reactive alkene cyclopropene.

참고

Store at -20°C. Keep tightly closed in a dry and cool place. Keep in properly labeled containers. Keep containers tightly closed in a cool, well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Incompatible with strong oxidizing agents, boron trifluoride, sulfuric acid and nitric acid

참조 문헌

Kenji Uneyama.; Nobuyoshi Kamaki.; Akihiko Moriya.; Sigeru Torii. Tin(II)-aluminum-promoted allylation of aldehydes with allyl chloride in an aqueous solvent system. J. Org. Chem. 1985, 50 (25), 5396-5399.

Farley Fisher.; Douglas E. Applequist. Synthesis of 1-Methylcyclopropene. J. Org. Chem. 1965, 30 (6), 2089-2090.

Lithiation with LDA in THF at -78o generatesɑ-chloroallyllithium which can be ɑ-alkylated with primary bromides in high yield. Displacement of the resulting allylic chloride with a dialkyl cuprate to give, stereoselectively, an (E)-alkene, has been used in a pheromone synthesis: J. Org. Chem., 45, 1504 (1981).

Treatment with sodium bis(trimethylsilyl)amide gives the strained, highly reactive alkene cyclopropene. For details and Diels-Alder reactions, see: J. Org. Chem., 61, 6462 (1996).

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H225-H302-H312-H332-H315-H319-H341-H351-H335-H373

Highly flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. Suspected of causing genetic defects. Suspected of causing cancer. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure.

주의 설명서: P210-P260-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

Merck
14,289
바일슈타인
635704
위험 등급
3
포장 그룹
I
통합 관세 코드
2903.29
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
UC7350000

권장

  • A11494

    1-Chlorobutane, 99+%
  • A11766

    Allyl bromide, 99%, stab. with 300-1000ppm Propylene oxide
  • A12575

    1-Methylimidazole, 99%
  • A15026

    Allyl alcohol, 98+%
  • 33337

    Magnesium sulfate, anhydrous, 99.5% min

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