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75-84-3 - Neopentyl alcohol, 99% - 2,2-Dimethyl-1-propanol - A14390 - Alfa Aesar

A14390 Neopentyl alcohol, 99%

CAS 번호
75-84-3
동의어
2,2-Dimethyl-1-propanol

사이즈 가격 ($) 수량 재고 여부
25g 37.20
100g 91.20
500g 381.00
장바구니에 추가 대량 견적에 추가 항목 보기

Neopentyl alcohol, 99%

MDL
MFCD00004682
EINECS
200-907-3

화학적 특성

화학식
(CH3)3CCH2OH
화학 식량
88.15
융점
52-56°
비등점
111-114°
인화점
36°(96°F)
밀도
0.818
용해도
Soluble in water at (20°C 40 g/L), alcohol, and ether. Solubility in methanol is almost transparent.

용도

It is used in the Mitsunobu reaction of methyl salicylate coupling of sterically hindered substrates.

참고

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

참조 문헌

Sudhakar Bhandaru, et al. Synthesis of a C14',15' dihydro derivative of the south hexacyclic steroid unit of cephalostatin 1. Part I : regiospecific Rh[II]-mediated intermolecular oxygen alkylation of a primary neopentyl alcohol.Tetrahedron Lett.,1995,36(46), 8347-8350.

J. D. Slagle, et al. Mechanism of the triphenylphosphine-tetrachloromethane-alcohol reaction: pericyclic or clustered ion pairs?J. Org. Chem.,1981,46(17), 3526-3530.

A method has been described for conversion to the iodide using a combination of methyl iodide and triphenyl phosphite: Org. Synth. Coll., 6, 830 (1988).

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H228

Flammable solid.

주의 설명서: P210-P280a-P240-P241-P370+P378a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. In case of fire: Use for extinction: CO2, powder or water spray.

기타 참조

Merck
14,6457
바일슈타인
1730984
위험 등급
4.1
포장 그룹
II
통합 관세 코드
2905.19
TSCA(독성물질규제법)"
Yes

권장

최근에 본 것

화학물질

화학물질

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