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938-18-1 - 2,4,6-Trimethylbenzoyl chloride, 98+% - Mesitoyl chloride - Mesitylene-2-carbonyl chloride - A14407 - Alfa Aesar

A14407 2,4,6-Trimethylbenzoyl chloride, 98+%

CAS 번호
938-18-1
동의어
Mesitoyl chloride
Mesitylene-2-carbonyl chloride

사이즈 가격 ($) 수량 재고 여부
10g 78.10
50g 297.00
장바구니에 추가 대량 견적에 추가 항목 보기

2,4,6-Trimethylbenzoyl chloride, 98+%

MDL
MFCD00013650
EINECS
213-339-6

화학적 특성

화학식
C10H11ClO
화학 식량
182.65
비등점
143-146°/60mm
인화점
>110°(230°F)
밀도
1.10
굴절률
1.5290
감도
Moisture Sensitive
용해도
Reacts slowly with water.

용도

2,4,6-Trimethylbenzoyl chloride is used, in the presence of pyridine, to protect OH groups as mesitoate esters.

참고

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature: 2 - 8°C. Air and moisture sensitive. Store under nitrogen. Incompatible with strong oxidizing agent

참조 문헌

Greg A. Urove.; Dennis G. Peters. Electrochemical reduction of 2,4,6-trimethylbenzoyl chloride and 2,4,6-trimethylbenzaldehyde at carbon and mercury cathodes in acetonitrile. Electrochimica Acta. 1994, 39 (10), 1441-1450.

Thomas H. Jukes. PANTOTHENIC ACID AND THE FILTRATE (CHICK ANTI-DERMATITIS) FACTOR. J. Am. Chem. Soc. 1939, 61 (4), 975-976.

Has been used, in the presence of pyridine, to protect OH groups as mesitoate esters, very stable to base hydrolysis: J. Am. Chem. Soc., 91, 4318 (1969). The group can be removed reductively, e.g. with LiAlH4: J. Chem. Soc. (C), 2944 (1971), or AlH3: J. Org. Chem., 57, 3431 (1992).

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

주의 설명서: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
776108
위험 등급
8
포장 그룹
II
통합 관세 코드
2916.39
TSCA(독성물질규제법)"
No

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