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614-16-4 - Benzoylacetonitrile, 98+% - omega-Cyanoacetophenone - beta-Oxohydrocinnamonitrile - A14473 - Alfa Aesar

A14473 Benzoylacetonitrile, 98+%

CAS 번호
614-16-4
동의어
omega-Cyanoacetophenone
beta-Oxohydrocinnamonitrile

사이즈 가격 ($) 수량 재고 여부
5g 40.90
25g 164.00
100g 573.00
장바구니에 추가 대량 견적에 추가 항목 보기

Benzoylacetonitrile, 98+%

MDL
MFCD00001942
EINECS
210-369-1

화학적 특성

화학식
C9H7NO
화학 식량
145.16
융점
79-83°
비등점
159-160°/10mm
용해도
Slightly soluble in water.

용도

Benzoylacetonitrile is used to produce 2-benzoyl-3-furan-2-yl-acrylonitrile. It is also used in the synthesis of substituted naphtho[1,8-bc]pyrans and as building block in the preparation of 4H-pyrans, 2-pyridones, furans and carbocyclics. It is an active methylene compound, useful in heterocyclic synthesis, e.g. polyfunctional pyridines and pyrimidines.

참고

Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

참조 문헌

L P Davies.; S C Chow.; J H Skerritt.; D J Brown.; G A Johnston. Pyrazolo[3,4-d]pyrimidines as adenosine antagonists.. Life Sciences. 1984, 34 (22), 2117-2128.

Tarek S. Mansour. Hunig's base-magnesium chloride mediated carbon alkylation and oxygen acylation of benzoylacetonitrile. Tetrahedron Letters. 1988, 29 (28), 3437-3440.

Active methylene compound, useful in heterocyclic synthesis, e.g. polyfunctional pyridines and pyrimidines: Synthesis, 775 (1989). Reaction with tosic anhydride, followed by diethyl aminomalonate provides a short, facile synthesis of 3-aminopyrrole-2-carboxylates: J. Org. Chem., 65, 2603 (2000):

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H301-H315-H319-H335

Toxic if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P261-P280a-P301+P310a-P305+P351+P338-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
386745
포장 그룹
III
통합 관세 코드
2926.90
TSCA(독성물질규제법)"
Yes

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