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10035-10-6 - Hydrogen bromide, 33% w/w (45% w/v) soln. in acetic acid - Hydrobromic acid acetic acid solution - A14475 - Alfa Aesar

A14475 Hydrogen bromide, 33% w/w (45% w/v) soln. in acetic acid

CAS 번호
10035-10-6
동의어
Hydrobromic acid acetic acid solution

사이즈 가격 ($) 수량 재고 여부
100ml 34.30
500ml 117.00
2500ml 456.00
장바구니에 추가 대량 견적에 추가 항목 보기

Hydrogen bromide, 33% w/w (45% w/v) soln. in acetic acid

MDL
MFCD00011323
EINECS
233-113-0

화학적 특성

화학식
BrH
화학 식량
80.92
인화점
65°(149°F)
밀도
1.40
용해도
Miscible with water, alcohol and organic solvents.

용도

Hydrobromic acid is an indispensable raw material for organic intermediates, inorganic pharmaceuticals, photosensitive materials, dyes and medicines. It is also used in the production of bromine compounds. It is used as an important agent in the industrial processes of isomerization, polymerization, hydration and dehydration and esterification reactions. It plays an essential role for the extraction of mercury from the cinnebar ore.

참고

Air and light sensitive. Incompatible with strong bases, strong oxidizing agents, ammonia, ozone, fluorine, potassium permanganate, amines, alcohols and metals.

참조 문헌

Preferred reagent for the non-hydrogenolytic cleavage of the N-benzyloxycarbonyl (Cbz, Z) group in peptide synthesis: J. Org. Chem., 17, 1564 (1952). For peptide reagents, see Appendix 6.

Used in combination with Paraformaldehyde, A11313, or 1,3,5-Trioxane, A15639, for the bromomethylation of aromatics: J. Org. Chem., 58, 1262 (1993); Synlett, 55 (1989). For N-bromomethylation of phthalimide and other imides, see: Synlett, 933 (1994).

For use in the bromoacetoxylation of (S)-(+)-1,2-Propanediol, B21773, as an example of the conversion of chiral vic-diols to epoxides with retention of configuration, see: J. Chem. Soc., Perkin 1, 1214 (1973); Org. Synth. Coll., 7, 356 (1990).

Cai, X.; Li, Y.; Yue, D.; Yi, Q.; Li, S.; Shi, D.; Gu, Z. Reversible PEGylation and Schiff-base linked imidazole modification of polylysine for high-performance gene delivery. J. Mater. Chem. B 2015, 3 (8), 1507-1517.

Wang, Q. M.; Gao, Z.; Liu, S.; Fan, B.; Kang, L.; Huang, W.; Jin, M. Hybrid polymeric micelles based on bioactive polypeptides as pH-responsive delivery systems against melanoma. Biomaterials 2014, 35 (25), 7008-7021.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H227-H303-H312-H331-H314-H318-H335

Combustible liquid. May be harmful if swallowed. Harmful in contact with skin. Toxic if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. May cause respiratory irritation.

주의 설명서: P210u-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

Merck
14,4778
바일슈타인
3587158
위험 등급
8
포장 그룹
II
통합 관세 코드
2811.19
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
MW3850000

권장

최근에 본 것

화학물질

화학물질

금속 및 재료

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