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87-62-7 - 2,6-Dimethylaniline, 99% - 2,6-Xylidine - A14512 - Alfa Aesar

A14512 2,6-Dimethylaniline, 99%

CAS 번호
87-62-7
동의어
2,6-Xylidine

사이즈 가격 ($) 수량 재고 여부
100g 20.80
500g 57.60
1000g 109.00
장바구니에 추가 대량 견적에 추가 항목 보기

2,6-Dimethylaniline, 99%

MDL
MFCD00007747
EINECS
201-758-7

화학적 특성

화학식
C8H11N
화학 식량
121.18
융점
11°
비등점
216°
인화점
91°(195°F)
밀도
0.981
굴절률
1.5600
용해도
Slightly miscible with water. Miscible with ethanol and diethyl ether.

용도

2,6-Dimethylaniline is used in pharmaceuticals, as dye intermediates and in organic synthesis. It is also used in the production of antioxidants, agricultural, pharmaceutical, rubber chemicals and other target organic molecules.

참고

It is sensitive to air and light. Incompatible withacids, acid chlorides, acid anhydrides, oxidizing agents, chloroformates and halogens.

참조 문헌

Hindered aromatic amines do not form imines by direct reaction with benzophenones. An indirect route involves formation of the imine with an aldehyde, introduction of the second aryl group by 1,2-addition of the aryllithium and dehydrogenation of the resulting secondary amine with DDQ: J. Org. Chem., 54, 2464 (1989).

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Huang, W. C.; Lin, Y. C. ; Tzeng, W. B. Mass-analyzed threshold ionization spectroscopy of 2,6-dimethylaniline, 2,6-dimethylaniline-NHD, and 2,6-dimethylaniline-ND2. Chem. Phys. Lett. 2012, 551, 50-53.

Ting, W-P.; Huang, Y-H.; Lu, M-C. Oxidation of 2,6-dimethylaniline by the Fenton, electro-Fenton and photoelectro-Fenton processes. J. Environ. Sci. Health, Part A 2011, 46 (10), 1085-1091.

Gockel, S. N.; Hull, K. L. Chloroform as a Carbon Monoxide Precursor: In or Ex Situ Generation of CO for Pd-Catalyzed Aminocarbonylations. Org. Lett. 2015, 17 (13), 3236-3239.

Yao, Q.; Wang, Z.; Zhang, Y.; Liu, X.; Lin, L.; Feng, X. N,N'-Dioxide/Gadolinium(III)-Catalyzed Asymmetric Conjugate Addition of Nitroalkanes to α, β-Unsaturated Pyrazolamides. J. Org. Chem. 2015, 80 (11), 5704-5712.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H227-H302-H312-H332-H315-H351-H335

Combustible liquid. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Suspected of causing cancer. May cause respiratory irritation.

주의 설명서: P260-P262-P273-P280h

Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Avoid release to the environment. Wear protective gloves/clothing.

기타 참조

Merck
14,10084
바일슈타인
636332
위험 등급
6.1
포장 그룹
II
통합 관세 코드
2921.49
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
ZE9275000

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