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941-69-5 - N-Phenylmaleimide, 98+% - 1-Phenyl-1H-pyrrole-2,5-dione - A14616 - Alfa Aesar

A14616 N-Phenylmaleimide, 98+%

CAS 번호
941-69-5
동의어
1-Phenyl-1H-pyrrole-2,5-dione

사이즈 가격 ($) 수량 재고 여부
25g 48.90
100g 126.00
500g 523.00
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N-Phenylmaleimide, 98+%

MDL
MFCD00005502
EINECS
213-382-0

화학적 특성

화학식
C10H7NO2
화학 식량
173.17
융점
87-91°
비등점
162-163°/12mm
용해도
Soluble in water (slightly ), methanol, ethanol, and benzene.

용도

N-Phenylmaleimide is used as a dipolarophile in 1,3-cycloaddition reaction with a nitrone, useful for the preparation of crystalline adducts of dienes. It is used as a plastic modifier.

참고

Store in cool, dry conditions in a well sealed container. Store away from oxidizing agents.

참조 문헌

Yoshio Okamoto; Tamali Nakano; Hiroyuki Kobayashi; Koichi Hatada. Asymmetric polymerization of N-phenylmaleimide. Polymer Bulletin. 1991, 25 (1), 5-8.

Takao Iijima; Tsutomu Nishina; Wakichi Fukuda and Masao Tomoi. Effect of matrix compositions on modification of bismaleimide resin by N-phenylmaleimide-styrene copolymers. Journal of Applied Polymer Science. 1996, 60 (1), 37-45.

Dienophile useful for the preparation of crystalline adducts of dienes.

Used as a dipolarophile in 1,3-cycloaddition reaction with a nitrone, generated in situ: Org. Synth. Coll., 5, 957 (1973). Traps stereoselectively the small proportion of azomethine ylide in equilibrium with the imines of ɑ-amino acids: Tetrahedron, 44, 1523 (1988):

1,3-Dipoles can also be generated by F- induced elimination: Org. Synth. Coll., 8, 231 (1993):

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H301-H319

Toxic if swallowed. Causes serious eye irritation.

주의 설명서: P280i-P301+P310a-P305+P351+P338-P321-P405-P501a

Wear eye/face protection. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment (see label). Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

Merck
14,7299
바일슈타인
125098
위험 등급
6.1
포장 그룹
III
통합 관세 코드
2925.19
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
ON5950000

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