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59-88-1 - Phenylhydrazine hydrochloride, 99% - A14645 - Alfa Aesar

A14645 Phenylhydrazine hydrochloride, 99%

CAS 번호
59-88-1
동의어

사이즈 가격 ($) 수량 재고 여부
100g 61.40
장바구니에 추가 대량 견적에 추가 항목 보기

Phenylhydrazine hydrochloride, 99%

MDL
MFCD00012924
EINECS
200-444-7

화학적 특성

화학식
C6H8N2•HCl
화학 식량
144.61
융점
ca 252° dec.
용해도
Soluble in water and alcohol.

용도

Phenylhydrazine hydrochloride is used as a selective mannosidase inhibitor. It is used in the study of tyrosine phosphorylation of janus protein tyrosine kinase in the EPO-responsive normal erythroblastoid cells of anemic mice. It is used in steroid assays and as an N-protecting reagent. Its free base, phenylhydrazine is used to prepare indoles, which find application as intermediates in the synthesis of various dyes and pharmaceuticals.

참고

Air and light sensitive. Hygroscopic. Store in cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and bases.

참조 문헌

Butin, A. V.; Uchuskin, M. G.; Pilipenko, A. S.; Serdyuk, O. V.; Trushkov, I. V. Unusual reactivity of beta-(3-indolyl)-alpha, beta-unsaturated ketones. 2-Acetylvinyl group removal by phenylhydrazine hydrochloride. Tetrahedron Lett. 2011, 52 (41), 5255-5258.

Muralirajan, K.; Haridharan, R.; Prakash, S.; Cheng, C. H. Rhodium(III)-Catalyzed in situ Oxidizing Directing Group-Assisted C? H Bond Activation and Olefination: A Route to 2-Vinylanilines. Adv. Synth. Catal. 2015, 357, (4), 761-766.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H301-H311-H331-H315-H319-H317-H341-H350-H372

Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. Suspected of causing genetic defects. May cause cancer. Causes damage to organs through prolonged or repeated exposure.

주의 설명서: P260-P201-P301+P310a-P305+P351+P338-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

Merck
14,7293
바일슈타인
3594958
위험 등급
6.1
포장 그룹
III
통합 관세 코드
2928.00
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
MV9000000

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