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367-57-7 - 1,1,1-Trifluoro-2,4-pentanedione, 98% - Tfpd-H - 1,1,1-Trifluoroacetylacetone - A14682 - Alfa Aesar

A14682 1,1,1-Trifluoro-2,4-pentanedione, 98%

CAS 번호
367-57-7
동의어
Tfpd-H
1,1,1-Trifluoroacetylacetone

사이즈 가격 ($) 수량 재고 여부
5g 22.40
25g 75.50
100g 255.00
장바구니에 추가 대량 견적에 추가 항목 보기

1,1,1-Trifluoro-2,4-pentanedione, 98%

MDL
MFCD00000427
EINECS
206-698-5

화학적 특성

화학식
CF3COCH2COCH3
화학 식량
154.09
비등점
105-107°
인화점
26°(79°F)
밀도
1.274
굴절률
1.3890
용해도
Soluble in water (slightly) and many organic solvents.

용도

1,1,1-Trifluoro-2,4-pentanedione has been used as reagent in the preparation of 2-alkylcarbonyl and 2-benzoyl-3-trifluoromethylquinoxaline 1,4-di-N-oxide derivatives.

참고

Stable under recommended storage conditions. Incompatible with oxidizing agents.

참조 문헌

Belen Zarranz; Andres Jaso; Ignacio Aldana; Antonio Monge. Synthesis and anticancer activity evaluation of new 2-alkylcarbonyl and 2-benzoyl-3-trifluoromethyl-quinoxaline 1,4-di-N-oxide derivatives. Bioorganic & Medicinal Chemistry. 2004, 12, (13),3711-3721

 

Mansoureh Zahedi-Tabrizi; Fariba Tayyari; Zainab Moosavi-Tekyeh; Alireza Jalali; Sayyed Faramarz Tayyari. Structure and vibrational assignment of the enol form of 1,1,1-trifluoro-2,4-pentanedione. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2006, 65, (2),387-396

Chelating ligand. Review of chemistry of fluorinated ß-diketones: Russ. Chem. Rev., 50, 180 (1981).

For use in the preparation of trifluoromethyl pyrimidines by reaction with guanidines, see: Synth. Commun., 20, 913 (1990):

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H226-H302-H315-H319-H335

Flammable liquid and vapour. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
1705177
위험 등급
3
포장 그룹
III
통합 관세 코드
2914.79
TSCA(독성물질규제법)"
Yes

권장

  • A10112

    1,1,1-Trifluoro-5,5-dimethyl-2,4-hexanedione, 95%
  • A10264

    2-Hydroxy-5-nitrobenzaldehyde, 98%
  • A10288

    o-Anisidine, 99%
  • L01693

    1,1,1,5,5,5-Hexafluoro-2,4-pentanedione, 98+%
  • 11048

    Potassium tetrachloroplatinate(II), 99.9% (metals basis), Pt 46.0% min

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