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768-90-1 - 1-Bromoadamantane, 99% - 1-Adamantyl bromide - A14893 - Alfa Aesar

A14893 1-Bromoadamantane, 99%

CAS 번호
768-90-1
동의어
1-Adamantyl bromide

사이즈 가격 ($) 수량 재고 여부
25g 30.70
100g 100.00
장바구니에 추가 대량 견적에 추가 항목 보기

1-Bromoadamantane, 99%

MDL
MFCD00074721
EINECS
212-200-7

화학적 특성

화학식
C10H15Br
화학 식량
215.14
융점
117-121°
용해도
It is soluble in organic solvents and insoluble in water.

용도

1-Bromoadamantane is an important intermediate, used in synthesizing medicines and new materials etc.

참고

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Moisture sensitive. Keep away from Strong oxidizing agents.

참조 문헌

SL Regen .;  JJ Besse .;  J McLick. Solid-phase cosolvents. Triphase catalytic hydrolysis of 1-bromoadamantane. Journal of the American Chemical. 1979 101, (1), 116-120.

SL Regen.; L Dulak. Solid-phase cosolvents. Journal of the American Chemical society. 197799, (2), 623-625.

Reduction with Tri-n-butyl­tin hydride, A13298, generates the 1-adamantyl radical which, e.g. adds to Michael acceptors in good yield: J. Org. Chem., 53, 1285 (1988).

With activated Ca metal (prepared from CaBr2 and Li biphenylide), forms an organocalcium reagent which reacts with ketones to give tertiary alcohols; the preparation and reactivity of these intermediates is discussed: Org. Synth. Coll., 9, 9 (1998).

Undergoes Heck-type coupling with styrenes and arenes, catalyzed by Pd on carbon: Synthesis, 148 (1998).

기타 참조

바일슈타인
1098857
통합 관세 코드
2903.89
TSCA(독성물질규제법)"
No

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