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100-85-6 - Benzyltrimethylammonium hydroxide, 40% w/w in methanol - Triton B - A14927 - Alfa Aesar

A14927 Benzyltrimethylammonium hydroxide, 40% w/w in methanol

CAS 번호
100-85-6
동의어
Triton B

사이즈 가격 ($) 수량 재고 여부
100ml 25.80
500ml 73.80
2500ml 282.00
장바구니에 추가 대량 견적에 추가 항목 보기

Benzyltrimethylammonium hydroxide, 40% w/w in methanol

MDL
MFCD00008281
EINECS
202-895-5

화학적 특성

화학식
C10H17NO
화학 식량
167.25
비등점
65°
인화점
15°(59°F)
밀도
0.920
굴절률
1.4270
감도
Air Sensitive
용해도
Miscible with water, hydrocarbons, aromatic hydrocarbons and halogenated solvents.

용도

Benzyltrimethylammonium hydroxide is used as a phase-transfer catalyst. It is also used in aldol condensation reactions and base-catalyzed dehydration reactions. Further, it serves as a strong organic base and used in Horner-Wadsworth-Emmons olefination reactions. In addition, it is an active component in the formulation, which is used in silicon wafer cleaning applications.

참고

Air Sensitive. Incompatible with strong oxidizing agents.

참조 문헌

Triton® is a registered trademark of Rohm and Haas Co.

Useful base catalyst or reagent for many reactions. For use in the Michael addition of nitro-compounds to ɑß-unsaturated esters, see: Org. Synth. Coll., 4, 652 (1963). For C-methylation of 2-Methyl­cyclohexane-1,3-dione, A11218 , see: Org. Synth. Coll., 8, 312 (1993).

Grimaldi, T. B.; Back, D. F.; Zeni, G. Synthesis of Naphthofurans by tBuOK-Catalyzed Intramolecular Anionic Cycloaddition of Unsymmetrical Bis-propargyl Ethers. Eur. J. Org. Chem. 2015, 2015 (31), 6924-6931.

Periyasamy, T.; Asrafali, S. P.; Muthusamy, S. New benzoxazines containing polyhedral oligomeric silsesquioxane from eugenol, guaiacol and vanillin. New J. Chem. 2015, 39 (3), 1691-1702.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H225-H311-H331-H314-H318-H370

Highly flammable liquid and vapour. Toxic in contact with skin. Toxic if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Causes damage to organs.

주의 설명서: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
3917256
위험 등급
3
포장 그룹
II
통합 관세 코드
2923.90
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
BO8575000

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