Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

630-19-3 - Trimethylacetaldehyde, 95% - Pivaldehyde - A15013 - Alfa Aesar

A15013 Trimethylacetaldehyde, 95%

CAS 번호
630-19-3
동의어
Pivaldehyde

사이즈 가격 ($) 수량 재고 여부
5g 58.00
25g 185.00
100g 582.00
장바구니에 추가 대량 견적에 추가 항목 보기

Trimethylacetaldehyde, 95%

MDL
MFCD00006962
EINECS
211-134-6

화학적 특성

화학식
C5H10O
화학 식량
86.13
융점
비등점
74-76°
인화점
-15°(5°F)
밀도
0.775
굴절률
1.3794
감도
Air Sensitive
용해도
It is virtually insoluble in water but soluble in chloroform.

용도

Trimethylacetaldehyde is used as a stereoselective synthesis application. It is also used as a building block used in aldol condensation reactions. It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and Dyestuff.

참고

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature: 2 - 8°C. Keep away from oxidizing agents, strong reducing agents.

참조 문헌

Anna K. Szardenings.; Timothy S. Burkoth.; Gary C. Look.; David A. Campbell. A Reductive Alkylation Procedure Applicable to Both Solution- and Solid-Phase Syntheses of Secondary Amines. J. Org. Chem. 1996, 61, (19), 6720-6722.

Samiran Bhattacharjee.; Kwang-Eun Jeong.; Soon-Yong Jeong.; Wha-Seung Ahnl. Synthesis of a sulfonato-salen-nickel(II) complex immobilized in LDH fortetralin oxidation. New J. Chem. 2010, 34, 156-162.

Derivatizing agent for amino acids, forming oxazolidinones as volatile derivatives for GC: Anal. Biochem., 49, 442 (1972); Aust. J. Biol. Sci., 26, 831 (1973).

For formation of the fused pyrrolidino-oxazolidinone from L-proline, catalyzed by trifluoroacetic acid, and use of the product in a synthesis of ɑ-branched amino acids, see: Org. Synth. Coll., 9, 626 (1998):

For use in the protection of asparagine as a tetrahydropyrimidinone derivative, see: Org. Synth. Coll., 9, 17 (1998). For use of this system in ɑ-alkylation of (S)-asparagine with self-regeneration of the stereogenic center, see: J. Org. Chem., 63, 4706 (1998).

Promotes the epoxidation of alkenes with molecular oxygen: Tetrahedron Lett., 33, 6827 (1992).

The imine formed with ethylamine has been used to convert aryl chlorides to the hindered tertiary amides: N-ethyl-N-(1-methoxy-2,2-dimethylpropyl)benzamides, which can be ortho metallated cleanly at higher temperatures than other amide systems: J. Org. Chem., 60, 8417 (1995).

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H225

Highly flammable liquid and vapour.

주의 설명서: P210-P243-P403

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Take precautionary measures against static discharge. Store in a well-ventilated place.

기타 참조

바일슈타인
506060
위험 등급
3
포장 그룹
II
통합 관세 코드
2912.19
TSCA(독성물질규제법)"
Yes

권장

최근에 본 것

화학물질

화학물질

금속 및 재료

촉매

분석 기기 및 실험실 용품