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A15120 (Iodomethyl)trimethylsilane, 99%

CAS 번호
4206-67-1
동의어
Trimethylsilylmethyl iodide

Stock No. 사이즈 가격 ($) 수량 재고 여부
A15120-09 10g 77.90
A15120-18 50g 254.00
장바구니에 추가 대량 견적에 추가 항목 보기

(Iodomethyl)trimethylsilane, 99%

MDL
MFCD00001077
EINECS
224-123-6

화학적 특성

화학식
C4H11ISi
화학 식량
214.12
비등점
140-142°
인화점
31°(88°F)
밀도
1.443
굴절률
1.4915
Storage & Sensitivity
Light Sensitive. Ambient temperatures.
용해도
Difficult to mix.

용도

(Iodomethyl)trimethylsilane is used for the N-alkylation of amides, in a reaction sequence to prepare unstabilized ylides for [2+3]-cycloadditions. It can react with acetoacetic acid ethyl ester to get 3-trimethylsilanyl-proπonic acid ethyl ester.

참고

Light Sensitive. Store in cool, dry conditions in well sealed containers. Keep container tightly closed.

참조 문헌

Motoo Tori.; Chiho Makino.; Kenji Hisazumi.; Masakazu Sono.; Katsuyuki Nakashima. Synthesis of a homochiral ketone having a pinguisane skeleton using phenylethylamine as a chiral auxiliary: a formal total synthesis of deoxopinguisone. Tetrahedron: Asymmetry. 2001, 12, (2), 301-307.

Dale L. Boger.; Louis R. Cerbone.; Daniel Yohannes. Oxidative coupling of methyl 6-hydroxyindole-2-carboxylate with primary amines. Preparation of 2-substituted methyl pyrrolo[2,3-e]benzoxazole-5-carboxylates. J. Org. Chem. 1988, 53, (21), 5163-5166.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

기타 참조

바일슈타인
1731485
위험 등급
3
포장 그룹
III
통합 관세 코드
2931.90
TSCA(독성물질규제법)"
No

권장

  • A10456

    Dibromomethane, 99%, stab. with 50ppm BHT
  • A10644

    Methyl diethylphosphonoacetate, 97%
  • A11471

    Boron trifluoride-acetic acid complex,35-36.5% BF3
  • A12253

    Salicylic acid, 99%
  • A12704

    Potassium iodide, 99%

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화학물질

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