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123-11-5 - 4-Methoxybenzaldehyde, 98% - p-Anisaldehyde - A15364 - Alfa Aesar

A15364 4-Methoxybenzaldehyde, 98%

CAS 번호
123-11-5
동의어
p-Anisaldehyde

사이즈 가격 ($) 수량 재고 여부
50g 19.10
250g 36.00
1000g 88.10
장바구니에 추가 대량 견적에 추가 항목 보기

4-Methoxybenzaldehyde, 98%

MDL
MFCD00003385
EINECS
204-602-6

화학적 특성

화학식
C8H8O2
화학 식량
136.15
융점
0-2°
비등점
247-249°
인화점
116°(241°F)
밀도
1.121
굴절률
1.5730
감도
Air & Light Sensitive
용해도
Miscible with acetone, alcohol, ether, chloroform and benzene. Immiscible with water.

용도

4-Methoxybenzaldehyde is widely utilized in the fragrance and flavor industry. It finds application as an important intermediate in the synthesis of other organic compounds, perfumes and pharmaceuticals like antihistamines. It is also used in the preparation of agrochemicals, dyes and plastic additives. A solution of para-anisaldehyde with acid and ethanol is used as stain in thin layer chromatography (TLC), which provides easy identification of different compounds.

참고

Air and Light Sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong bases, strong oxidizing agents and strong reducing agents.

참조 문헌

Diols, under acid catalysis, can be protected as 4-methoxybenzylidene cyclic acetals, hydolyzed ca 10x faster by acid than the benzylidene acetal: J. Am. Chem. Soc., 84, 430 (1962). Cleavage with Ce(IV): J. Chem. Soc., Chem. Commun., 2010 (1984), hydrogenolysis: Tetrahedron Lett., 32, 6155 (1991), or DibalH: Tetrahedron Lett., 28, 3835 (1987); Tetrahedron: Asymmetry, 6, 2319 (1995) have also been reported. See also 4-Methoxybenzaldehyde dimethyl­ acetal, A15793.

/n

Brullo, C.; Massa, M.; Rocca, M.; Rotolo, C.; Guariento, S.; Rivera, D.; Ricciarelli, R.; Fedele, E.; Fossa, P.; Bruno, O. Synthesis, Biological Evaluation, and Molecular Modeling of New 3-(Cyclopentyloxy)-4-methoxybenzaldehyde O-(2-(2,6-Dimethylmorpholino)-2-oxoethyl) Oxime (GEBR-7b) Related Phosphodiesterase 4D (PDE4D) Inhibitors. J. Med. Chem. 2014, 57 (16), 7061-7072.

Denizalti, S.; Turkmen, H.; Cetinkaya, B. Chelating alkoxy NHC-Rh(I) complexes and their applications in the arylation of aldehydes. Tet. Lett. 2014, 55 (30), 4129-4132.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H302

Harmful if swallowed.

주의 설명서: P264-P270-P301+P312a-P330-P501a

Wash thoroughly after handling. Do not eat, drink or smoke when using this product. IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

Merck
14,663
바일슈타인
471382
통합 관세 코드
2912.49
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
BZ2625000

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