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100-00-5 - 1-Chloro-4-nitrobenzene, 98+% - 4-Nitrochlorobenzene - A15396 - Alfa Aesar

A15396 1-Chloro-4-nitrobenzene, 98+%

CAS 번호
100-00-5
동의어
4-Nitrochlorobenzene

사이즈 가격 ($) 수량 재고 여부
250g 18.30
1000g 39.70
5000g 158.00
장바구니에 추가 대량 견적에 추가 항목 보기

1-Chloro-4-nitrobenzene, 98+%

MDL
MFCD00007285
EINECS
202-809-6

화학적 특성

화학식
C6H4ClNO2
화학 식량
157.56
융점
82-86°
비등점
238-242°
인화점
127°(260°F)
밀도
1.515
용해도
Soluble in boiling hot ethanol, ether, toluene, acetone, organic solvents and carbon disulfide. Sparingly soluble in cold alcohol. Insoluble in water.

용도

1-Chloro-4-nitrobenzene is an important intermediate used in the preparation of 2,4-dinitrochlorobenzene and 3,4-dichloronitrobenzene. It is used as a raw material in the preparation of 4-nitrodiphenylamine, 4-chloroaninline and (4-[(4-aminobenzene)sulfonyl]aniline). It serves as a common antioxidant, which is found in rubber.

참고

Incompatible with strong oxidizing agents and strong bases.

참조 문헌

The Cl substituent is activated to nucleophilic substitution by the p-nitro-group, and can be displaced under relatively mild conditions. For displacement by phenoxide, see: Org. Synth. Coll., 2, 445 (1943). For displacement by alkoxide in good yield, in the presence of TBAB or 18-crown-6, see: J. Org. Chem., 48, 3022 (1983).

Büldt, L. A.; Prescimone, A.; Neuburger, M.; Wenger, O. S. Photoredox Properties of Homoleptic d6 Metal Complexes with the Electron-Rich 4,4',5,5'-Tetramethoxy-2,2'-bipyridine Ligand. Eur. J. Inorg. Chem. 2015, 2015 (28), 4666-4677.

Zhuo, L.; Kou, K.; Yao, P.; Wu, G.; Wang, Y. Preparation and thermal decomposition kinetics research of pyridine-containing polyimide. J. Therm. Anal. Calorim. 2015, 119 (3), 2039-2051.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H301-H311-H331-H341-H351-H373

Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Suspected of causing genetic defects. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure.

주의 설명서: P260-P201-P280-P301+P310a-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER/doctor Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

Merck
14,2151
바일슈타인
508691
위험 등급
6.1
포장 그룹
II
통합 관세 코드
2904.99
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
CZ1050000

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