Used as a GC reagent for diols. It is a reagent used for palladium-catalyzed direct arylation, cyclopalladation, tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation, copper-mediated ligandless aerobic fluoroalkylation, Pd-catalyzed arylative cyclization, ruthenium catalyzed direct arylation, ligand-free copper-catalyzed coupling reactions and regioselective arylation and alkynylation by Suzuki-Miyaura and Sonogashira cross-coupling reactions. Also in as a reagent in the preparation of catalysts for Suzuki-Miyaura cross-coupling, palladium(II) thiocarboxamide complexes as Suzuki coupling catalysts, Biaryls by Suzuki reactions of aryl chlorides, bromides, and iodides with arylboronic acids.
Zhang, X-H.; Han, J-S.; Zhong, P. Pd-catalyzed direct arylation of phenylpyrazole: Synthesis of fipronil derivatives with aryl boronic acids promoted by a stoichiometric amount of NIS.J. Fluor. Chem.,2012,13744-49.
Pandiarajan, D.; Ramesh, R. Suzuki-Miyaura cross-coupling reaction of aryl bromides catalyzed by palladium(II) pyridoxal hydrazone complexes.J. Organomet. Chem.,2012,708-70918-24.
GC reagent for diols: J. Chromat., 158, 33 (1978); 186, 307 (1979). See also Appendix 5.
해저드 설명서 (EU): H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
주의 설명서: P261-P280a-P305+P351+P338-P304+P340-P405-P501a