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1193-18-6 - 3-Methyl-2-cyclohexen-1-one, 98% - A15704 - Alfa Aesar

A15704 3-Methyl-2-cyclohexen-1-one, 98%

CAS 번호
1193-18-6
동의어

사이즈 가격 ($) 수량 재고 여부
10g 66.70
25g 129.00
50g 241.00
100g 434.00
장바구니에 추가 대량 견적에 추가 항목 보기

3-Methyl-2-cyclohexen-1-one, 98%

MDL
MFCD00001581
EINECS
214-769-7

화학적 특성

화학식
C7H10O
화학 식량
110.15
비등점
199-200°
인화점
68°(154°F)
밀도
0.971
굴절률
1.4940
용해도
Soluble in alcohol. Insoluble in water.

용도

3-Methyl-2-cyclohexen-1-one was used in the synthesis of 19-nor-1α, 25-dihydroxyvitamin D(3) derivatives. It was also used in sex pheromone of the Douglas-fir beetle. Used in nut flavor.

참고

Store in cool, well ventilated area. Keep container tightly closed. Store away form oxidizing agent.

참조 문헌

X Zhou; G D Zhu; D Van Haver; M Vandewalle; P J De Clercq; A Verstuyf; R Bouillon. Synthesis, biological activity, and conformational analysis of four seco-D-15,19-bisnor-1alpha,25-dihydroxyvitamin D analogues, diastereomeric at C17 and C20. Journal of Medicinal Chemistry. 1999, 42 (18), 3539-3556.

Donald S. Noyce, Malcolm. Evett. Mechanism of the acid-catalyzed double bond migration in 3-cyclohexen-1-one and 3-methyl-3-cyclohexen-1-one. J. Org. Chem. 1972, 37 (3), 394-397.

For photochemical (2 + 2) photocycloaddition reaction with ethylene, as a general method for synthesis of fused cyclobutane systems, see: Org. Synth. Coll., 7, 315 (1990).

For conversion to the silyl enol ether and stereoselective aldol-type coupling, see: Tetrahedron, 45, 6101 (1989):

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H227-H302

Combustible liquid. Harmful if swallowed.

주의 설명서: P210u-P280a-P264-P301+P312a-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. Wash thoroughly after handling. IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
1560601
통합 관세 코드
2914.29
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
GW7340000

권장

최근에 본 것

화학물질

화학물질

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