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(Formylmethyl)triphenylphosphonium Chloride is a useful Wittig reagent. Used as a reactant for Hydroazidation reactions in preparation of a-azido alcohols, Preparation of prodrug (2-hydroxyamino-vinyl)-triphenyl-phosphonium (HVTP) inhibitor of peroxidase activity and apoptosis and Intramolecular [4 + 3] cycloaddition reactions.
Klaus Banert; Christian Berndt; Samia Firdous; Manfred Hagedorn; Young-Hyuk Joo; Tobias Rüffer; Heinrich Lang. Extremely simple but long overlooked: generation of α-azido alcohols by hydroazidation of aldehydes. Angewandte Chemie. International edition in English. 2010, 49 (52), 10206-10209.
Detcho A Stoyanovsky; Irina I Vlasova; Natalia A Belikova; Alexandr Kapralov; Vladimir Tyurin; Joel S Greenberger; Valerian E Kagan. Activation of NO donors in mitochondria: peroxidase metabolism of (2-hydroxyamino-vinyl)-triphenyl-phosphonium by cytochrome c releases NO and protects cells against apoptosis. FEBS Letters. 2008, 582 (5), 725-728.
Undergoes the Wittig reaction with aldehydes to give acrylic aldehydes either in the presence of base or by prior conversion to the phosphorane. For references see (Formylmethylene)triphenylphosphorane, A11709.
해저드 설명서 (EU): H302-H318
Harmful if swallowed. Causes serious eye damage.
주의 설명서: P280i-P264-P305+P351+P338-P310a-P301+P312a-P501a
Wear eye/face protection. Wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Dispose of contents/container in accordance with local/regional/national/international regulations.