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366-18-7 - 2,2'-Bipyridine, 99+% - 2,2'-Bipyridyl - 2,2'-Dipyridyl - A15782 - Alfa Aesar

A15782 2,2'-Bipyridine, 99+%

CAS 번호
366-18-7
동의어
2,2'-Bipyridyl
2,2'-Dipyridyl

사이즈 가격 ($) 수량 재고 여부
25g 52.20
100g 158.00
500g 526.00
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2,2'-Bipyridine, 99+%

MDL
MFCD00006212
EINECS
206-674-4

화학적 특성

화학식
C10H8N2
화학 식량
156.19
융점
70°
비등점
272-273°
인화점
121°(249°F)
용해도
Soluble in organic solvents and slightly soluble in water.

용도

Reagent for iron determinations.2,2'-bipyridine acts as a bidentate chelating ligand which form complexes with transition metal ions and shows antifungal, antibacterial and antiviral activity. It is used for the colorimetric determination of iron as well as oxidation reduction indicators to confirm the presence of ferrous ion in soils. It forms complexes with ruthenium and platinum, exhibit intense luminescence, which may have practical applications. Copper(I) bipyridine complexes involved in the oxidation of alcohols under aerobic conditions.

참고

Keep container tightly closed in a dry and well-ventilated place. Keep away from sources of ignition.

참조 문헌

Reagent for iron. Chelating ligand.

For use as an alternative to phosphines in Heck type reactions, see: Synlett, 871 (1992).

Complex with Chromium(VI)­ oxide, 12522, has been used in a mild selective oxidation of alcohols to aldehydes and ketones: Acta Chem. Scand., 25, 1125 (1971).

/n

Valvekens, P.; Bloch, E. D.; Long, J. R.; Ameloot, R.; De Vos, D. E. Counteranion effects on the catalytic activity of copper salts immobilized on the 2,2'-bipyridine-functionalized metal-organic framework MOF-253. Catal. Today 2015, 246, 55-59.

Kageshima, Y.; Kumagai, H.; Minegishi, T.; Kubota, J.; Domen, K. A Photoelectrochemical Solar Cell Consisting of a Cadmium Sulfide Photoanode and a Ruthenium-2,2'-Bipyridine Redox Shuttle in a Non-aqueous Electrolyte. Angew. Chem. 2015, 127 (27), 7988-7992.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H301-H312

Toxic if swallowed. Harmful in contact with skin.

주의 설명서: P280h-P301+P310a-P312a-P321-P405-P501a

Wear protective gloves/clothing. IF SWALLOWED: Immediately call a POISON CENTER/doctor Call a POISON CENTER/doctor if you feel unwell. Specific treatment (see label). Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

Merck
14,3347
바일슈타인
113089
위험 등급
6.1
포장 그룹
III
통합 관세 코드
2933.39
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
DW1750000

권장

  • A10249

    Tetra-n-butylammonium bromide, 98+%
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    Pyridine-2-carboxaldehyde, 99%
  • A11591

    Ethylene glycol, 99%
  • A13163

    1,10-Phenanthroline, 99%, may contain up to 1.5% water
  • 11043

    Ruthenium(III) chloride hydrate, 99.9% (PGM basis), Ru 38% min

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