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2186-92-7 - 4-Methoxybenzaldehyde dimethyl acetal, 98% - p-Anisaldehyde dimethyl acetal - A15793 - Alfa Aesar

A15793 4-Methoxybenzaldehyde dimethyl acetal, 98%

CAS 번호
2186-92-7
동의어
p-Anisaldehyde dimethyl acetal

사이즈 가격 ($) 수량 재고 여부
25g 40.20
250g 224.00
500g 407.00
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4-Methoxybenzaldehyde dimethyl acetal, 98%

MDL
MFCD00036507
EINECS
218-577-4

화학적 특성

화학식
C10H14O3
화학 식량
182.22
비등점
253°
인화점
97°(206°F)
밀도
1.068
굴절률
1.5055
용해도
Miscible with alcohol and many organic solvents. Slightly miscible with water.

용도

4-Methoxybenzaldehyde dimethyl acetal is used as a precursor to 1-methoxy-1-(4-methoxyphenyl)hept-2-yne, 2,5-dioxopyrrolidin-1-yl-3-((4R)-2-(4-methoxyphenyl)-5,5-dimethyl-1,3-dioxane-4-carboxamido)propanoate and 1-(p-anisyl)-2-(2-methoxyethyl)-3-phenylindene. Further, it acts as a protecting group reagent for diols, especially in carbohydrates. It is also used as a flavor essence in sunflower, cyclamen and in jasmine. In addition to this, it is involved in allylation reactions with allyltrimethylsilane catalyzed by Iron(III) chloride.

참고

Incompatible with strong oxidizing agents, strong acids and strong bases. Store in a cool place.

참조 문헌

Reagent for the protection of diols as their cyclic acetals, hydrolyzed ca 10x faster by acid than the benzylidene acetal: Rec. Trav. Chim., 103, 335 (1984); J. Chem. Soc., Perkin 1, 2371 (1984).

Li, Q. F.; Lin, H. X.; Cui, Y. M.; Xu, P. P. Syntheses and biological evaluation of C-3'-N-acyl modified taxane analogues from 1-deoxybaccatin-VI. Eur. J. Med. Chem. 2015, 104, 97-105.

Li, P.; Yu, Y.; Huang, P. P.; Liu, H.; Cao, C. Y.; Song, W. G. Core-shell structured MgAl-LDO@Al-MS hexagonal nanocomposite: an all inorganic acid-base bifunctional nanoreactor for one-pot cascade reactions. J. Mater. Chem. A 2014, 2 (2), 339-344.

기타 참조

바일슈타인
2048930
통합 관세 코드
2911.00
TSCA(독성물질규제법)"
Yes

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