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106-38-7 - 4-Bromotoluene, 98% - 4-Methylbromobenzene - A15843 - Alfa Aesar

A15843 4-Bromotoluene, 98%

CAS 번호
106-38-7
동의어
4-Methylbromobenzene

사이즈 가격 ($) 수량 재고 여부
25g 20.80
100g 41.50
500g 115.00
장바구니에 추가 대량 견적에 추가 항목 보기

4-Bromotoluene, 98%

MDL
MFCD00000109
EINECS
203-391-8

화학적 특성

화학식
C7H7Br
화학 식량
171.04
융점
26-29°
비등점
183-184°
인화점
85°(185°F)
밀도
1.410
용해도
Insoluble in water. Soluble in methanol.

용도

4-Bromotoluene was used in the synthesis of ketones by Cu/Pd-catalyzed decarboxylative cross-coupling reaction. 4-Bromotoluene undergoes Heck reaction with styrene in the presence of in situ generated palladium complexes of phosphine-functionalized N-heterocyclic carbene ligands.

참고

Store at room temperature. Keep away from oxidizing agents.

참조 문헌

Louis-Charles Campeau.; Sophie Rousseaux.; Keith Fagnou. A Solution to the 2-Pyridyl Organometallic Cross-Coupling Problem:? Regioselective Catalytic Direct Arylation of Pyridine N-Oxides. J. Am. Chem. Soc. 2005, 127 (51),18020-18021 .

Janis Louie.; John F. Hartwig. Discrete High Molecular Weight Triarylamine Dendrimers Prepared by Palladium-Catalyzed Amination.J. Am. Chem. Soc. 1997, 119 (48),11695-11696 .

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H301-H315-H319-H335

Toxic if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P261-P280a-P301+P310a-P305+P351+P338-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

Merck
14,1439
바일슈타인
1903636
통합 관세 코드
2903.99
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
XS7965600

권장

최근에 본 것

화학물질

화학물질

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