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6651-36-1 - 1-(Trimethylsiloxy)cyclohexene, 98% - 1-Cyclohexenyloxytrimethylsilane - A16099 - Alfa Aesar

A16099 1-(Trimethylsiloxy)cyclohexene, 98%

CAS 번호
6651-36-1
동의어
1-Cyclohexenyloxytrimethylsilane

사이즈 가격 ($) 수량 재고 여부
10g 47.90
50g 170.00
250g 776.00
장바구니에 추가 대량 견적에 추가 항목 보기

1-(Trimethylsiloxy)cyclohexene, 98%

MDL
MFCD00001541
EINECS
229-675-1

화학적 특성

화학식
C9H18OSi
화학 식량
170.33
비등점
165°
인화점
42°(107°F)
밀도
0.883
굴절률
1.4470
감도
Moisture Sensitive
용해도
Not miscible or difficult to mix.

용도

1-(Trimethylsiloxy)cyclohexene is used as intermediate to complex compounds, including natural products. It is also used as a pharmaceutical intermediate.

참고

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents. It is sensitive to moisture. Store under dry inert gas.

참조 문헌

Yea Shun Cheng.; Eugene Ho.; Patrick S. Mariano.; Herman L. Ammon. Mechanistic aspects of the boron trifluoride catalyzed, intermolecular Diels-Alder cycloaddition of an unactivated 2-aza 1,3-diene with electron-donating-substituted dienophiles. J. Org. Chem. 1985, 50 (26), 5678-5686.

Keiji Tanino.; Tadashi Shimizu.; Motoki Miyama.; Isao Kuwajima. A Novel [5+2] Cycloaddition Reaction Using a Dicobalt Acetylene Complex. J. Am. Chem. Soc. 2002, 122 (25), 6116-6117.

Silyl enol ethers undergo crossed aldol condensations with aldehydes and ketones: J. Am. Chem. Soc., 96, 7503 (1974); for tabulated results, see: Org. Synth. Coll., 8, 323 (1993):

Condensation with aldehydes is also promoted by F-, particularly TBAF: J. Org. Chem., 48, 932 (1983).

The Lewis acid-catalyzed condensation with nitroalkenes leads to 1,4-diketones: J. Am. Chem. Soc., 98, 4679 (1976); Org. Synth. Coll, 7, 414 (1990).

For reviews of the chemistry of silyl enol ethers, see: Synthesis, 91 (1977); 85 (1983).

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H226-H303

Flammable liquid and vapour. May be harmful if swallowed.

주의 설명서: P210-P280a-P240-P241-P303+P361+P353-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
1859394
위험 등급
3
포장 그룹
III
통합 관세 코드
2931.90
TSCA(독성물질규제법)"
Yes

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