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1779-58-4 - (Methoxycarbonylmethyl)triphenylphosphonium bromide, 98+% - (Carbomethoxymethyl)triphenylphosphonium bromide - Methyl (triphenylphosphonio)acetate bromide - A16301 - Alfa Aesar

A16301 (Methoxycarbonylmethyl)triphenylphosphonium bromide, 98+%

CAS 번호
1779-58-4
동의어
(Carbomethoxymethyl)triphenylphosphonium bromide
Methyl (triphenylphosphonio)acetate bromide

사이즈 가격 ($) 수량 재고 여부
25g 28.20
100g 83.00
500g 272.00
장바구니에 추가 대량 견적에 추가 항목 보기

(Methoxycarbonylmethyl)triphenylphosphonium bromide, 98+%

MDL
MFCD00011801
EINECS
217-222-0

화학적 특성

화학식
CH3O2CCH2P(C6H5)3Br
화학 식량
415.28
융점
ca 163° dec.
감도
Hygroscopic
용해도
Soluble in methanol(almost transparency).

용도

(Methoxycarbonylmethyl)triphenylphosphonium bromide is a reactant for the synthesis of GSK-3 inhibitors using the Wittig reaction, substituted furanones for antifungal and cytostatic activities, photochromic dithienylethene derivatives, gem-diiodoalkanes containing allylic alcohols and highly substituted cyclopentenes and brazilanes via Au-catalyzed deoxygenative Nazarov cyclization. As reactant for asymmetric hydrogenation of α,β-unsaturated ester-phosphonates, studies of thermal decomposition of phosphonium alkyl ester salts.

참고

Hygroscopic. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, water, moisture.

참조 문헌

Petr Šenel et. al. Antifungal 3,5-disubstituted furanones: From 5-acyloxymethyl to 5-alkylidene derivatives. Bioorganic & Medicinal Chemistry. 2010, 18 (5), 1988-2000.

Oliver Tosic et. al.Photochromic dithienylethenes with extended pi-systems. Photochemical & Photobiological Sciences. 2010, 9,(2), 128-130.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
3812975
통합 관세 코드
2931.39
TSCA(독성물질규제법)"
No

권장

  • A11021

    (1-Decyl)triphenylphosphonium bromide, 98%
  • A12470

    2-Vinylnaphthalene, 97%
  • A12753

    Propargyltriphenylphosphonium bromide, 97%
  • A14034

    Benzyltriphenylphosphonium chloride, 99%
  • A14380

    (Methoxymethyl)triphenylphosphonium chloride, 98+%

최근에 본 것

화학물질

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