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583-55-1 - 1-Bromo-2-iodobenzene, 98+%, stab. with copper - 2-Bromoiodobenzene - A17020 - Alfa Aesar

A17020 1-Bromo-2-iodobenzene, 98+%, stab. with copper

CAS 번호
583-55-1
동의어
2-Bromoiodobenzene

사이즈 가격 ($) 수량 재고 여부
5g 35.10
25g 120.00
100g 371.00
장바구니에 추가 대량 견적에 추가 항목 보기

1-Bromo-2-iodobenzene, 98+%, stab. with copper

MDL
MFCD00001030
EINECS
209-508-9

화학적 특성

화학식
C6H4BrI
화학 식량
282.91
융점
9-10°
비등점
257°
인화점
>110°(230°F)
밀도
2.256
굴절률
1.6645
감도
Light Sensitive
용해도
Not miscible or difficult to mix in water.

용도

2-Bromoiodobenzene is used in the synthesis of diarylamines.

참고

Light Sensitive. Protect from light. Store away from oxidizing agents.

참조 문헌

María E Budén.; Victoria A Vaillard.; Sandra E Martin.; Roberto A Rossi. Synthesis of carbazoles by intramolecular arylation of diarylamide anions.J Org Chem.2009,74(12), 4490-4498.

Biao Lu.; Bao Wang.; Yihua Zhang.; and Dawei Ma. CuI-Catalyzed Domino Process to 2,3-Disubstituted Benzofurans from 1-Bromo-2-Iodobenzenes and β-Keto Esters.J. Org. Chem.,2007,72,(14), 5337-5341.

Benzyne precursor. In the presence of excess of a Grignard reagent, the initially formed benzyne undergoes nucleophilic addition to give an ortho-substituted phenylmagnesium halide: Synth. Commun., 18, 1749 (1988).

Regioselective Suzuki coupling with arylboronic acids has been achieved giving 2-bromobiphenyl derivatives: Synlett, 207 (1992).

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H315-H319

Causes skin irritation. Causes serious eye irritation.

주의 설명서: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

기타 참조

바일슈타인
1855309
통합 관세 코드
2903.99
TSCA(독성물질규제법)"
Yes

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화학물질

화학물질

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