Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

63393-96-4 - Aliquat® 336 TG - Methyltri-n-octylammonium chloride - Tricaprylylmethylammonium chloride - A17247 - Alfa Aesar

A17247 Aliquat® 336 TG

CAS 번호
63393-96-4
동의어
Methyltri-n-octylammonium chloride
Tricaprylylmethylammonium chloride

사이즈 가격 ($) 수량 재고 여부
100ml 23.70
500ml 66.10
2500ml 250.00
장바구니에 추가 대량 견적에 추가 항목 보기

Aliquat® 336 TG

MDL
MFCD00011862
EINECS
264-120-7

화학적 특성

화학식
[CH3(CH2)7]3NCH3Cl
화학 식량
404.17
비등점
>240°
인화점
132°(269°F)
밀도
0.880
굴절률
1.4465
감도
Hygroscopic
용해도
Miscible with benzene and chloroform.

용도

Aliquat 336 is widely utilized as a phase transfer catalyst for the catalytic oxidation of cyclohexene to 1,6-hexanedioic acid. It is involved in the total synthesis of Manzamine A. It serves as an anti-static agent for textile fabrics and carpeting. It finds application in waste water treatment to control foaming. It has a major application as a metal extraction reagent for cadmium, zinc, iron and rare earth metals. It is used as an effective catalyst for the preparation of methylphenyl ether from sodium phenolate with for methyl bromide.

참고

Incompatible with strong oxidizing agents, acids and bases. BASF have renamed Aliquat 336 to Aliquat 336 TG due to reclassification under GHS / REACh because of the tertiary amine content. There is no change to the product's performance.

참조 문헌

Mixture of C8-C10; predominantly C8.

Aliquat is a registered trademark of Cognis Corporation.

Widely used lipophilic phase-transfer catalyst. Catalyzes the synthesis of long-chain alkyl azides from the bromides in water or formamide: Tetrahedron Lett., 30, 1245 (1989), the formation and saponification of hindered esters with KOH in the absence of solvent: J. Org. Chem., 51, 740 (1986), the solvent-free SNAr reactions of halopyridines: Heterocycles, 32, 1947 (1991), and dehydrohalogenation of vic-dibromides to alkynes: Org. Prep. Proced. Int., 21, 232 (1989). Catalyzes the solvent-free liquid-liquid phase-transfer hydroboration of olefins, using aqueous NaBH4: Synlett, 997 (2000). See Appendix 2.

Yokokita, T.; Kasamatsu, Y.; Yoshimura, T.; Takahashi, N.; Shinohara, A. Distribution Behavior of Nb, Ta, and Pa as Homologues of Db in Cation Exchange and Solid-Liquid and Liquid-Liquid Extractions by Aliquat 336 from Hydrochloric Acid. Solvent Extr. Ion Exch. 2015, 33 (5), 472-495.

Zhao, J.; Hu, Q.; Li, Y.; Liu, H. Efficient separation of vanadium from chromium by a novel ionic liquid-based synergistic extraction strategy. Chem. Eng. J. 2015, 264, 487-495.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H301-H314-H318-H361

Toxic if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage. Suspected of damaging fertility or the unborn child.

주의 설명서: P260u-P301+P310a-P303+P361+P353-P305+P351+P338-P405-P501a

Do not breathe dusts or mists. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

위험 등급
8
포장 그룹
III
통합 관세 코드
2923.90
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
BR8575000

권장

  • A11359

    Cyclohexene, 99%
  • A11618

    4-Methyl-2-pentanone, 99%
  • 12349

    Lead(II) chloride, Reagent Grade, 99%
  • 36622

    Sodium sulfide nonahydrate, ACS, 98.0% min
  • 41955

    Iodine, resublimed crystals, ACS, 99.8%

최근에 본 것

화학물질

화학물질

금속 및 재료

촉매

분석 기기 및 실험실 용품