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2687-43-6 - O-Benzylhydroxylamine hydrochloride, 99% - A17393 - Alfa Aesar

A17393 O-Benzylhydroxylamine hydrochloride, 99%

CAS 번호
2687-43-6
동의어

사이즈 가격 ($) 수량 재고 여부
5g 38.60
25g 130.00
100g 404.00
장바구니에 추가 대량 견적에 추가 항목 보기

O-Benzylhydroxylamine hydrochloride, 99%

MDL
MFCD00012952
EINECS
220-249-0

화학적 특성

화학식
C6H5CH2ONH2•HCl
화학 식량
159.62
융점
ca 238° subl.
감도
Hygroscopic
용해도
Soluble in DMSO and methanol.

용도

For use in the formation of nitrones from carbonyl compounds and their use in cycloaddition reactions. Used as a reagent used in the synthesis of hydroxylamines and hydroxyamates. Effective reagent used to prepare α-hydroxybenzylamines from α-hydroxyketones.

참고

Hygroscopic. Store away from water/moisture and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas. Protect from humidity.

참조 문헌

C. Liana Allen, et al. Transamidation of Primary Amides with Amines Using Hydroxylamine Hydrochloride as an Inorganic Catalyst.Angew. Chem. Int. Ed.,2012,51(6), 1383-1386.

Lidia De Luca, et al. An Easy and Convenient Synthesis of Weinreb Amides and Hydroxamates.J. Org. Chem.,2001,66(7), 2534-2537.

In the peptide field, Palladium, 11722 is a useful selective catalyst for deprotection of the benzyl hydroxamates: Tetrahedron Lett., 36, 197 (1995).

For use in the formation of nitrones from carbonyl compounds and their use in cycloaddition reactions, see: J. Org. Chem., 47, 2328 (1982); 52, 2179 (1987).

기타 참조

바일슈타인
3595440
통합 관세 코드
2922.50
TSCA(독성물질규제법)"
No
RTECS(화학물질 독성 등록)
NC3040000

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