Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

5419-55-6 - Triisopropyl borate, 98+% - Boric acid triisopropyl ester - Isopropyl borate - A17592 - Alfa Aesar

A17592 Triisopropyl borate, 98+%

CAS 번호
5419-55-6
동의어
Boric acid triisopropyl ester
Isopropyl borate

사이즈 가격 ($) 수량 재고 여부
100ml 42.70
500ml 96.80
2500ml 375.00
장바구니에 추가 대량 견적에 추가 항목 보기

Triisopropyl borate, 98+%

MDL
MFCD00008872
EINECS
226-529-9

화학적 특성

화학식
C9H21BO3
화학 식량
188.08
융점
-59°
비등점
139-141°
인화점
17°(62°F)
밀도
0.815
굴절률
1.3760
감도
Moisture Sensitive
용해도
Miscible with ether, ethanol, isopropanol and benzene.

용도

Triisopropyl borate is used as reagent in Pd-catalyzed coupling reaction with aryl halides such as Suzuki reaction. It is used as a reagent for the preparation of the boronic acids and esters; as a Lewis acid catalyst and involved in the ortho-borylation of 1-substituted naphthalenes. Furthermore, it plays an important role as a catalyst for the production of resins, waxes, paints and varnishes.

참고

Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents. Decomposes in water.

참조 문헌

Reagent for preparation of boronates from Grignard or organolithium reagents, often giving higher yields than other trialkyl borates: Organometallics, 2, 1316 (1983); Tetrahedron Lett ., 29, 2631 (1988).

Garcia-Alonso, D.; Potts, S. E.; van Helvoirt, C. A.; Verheijen, M. A.; Kessels, W. M. Atomic layer deposition of B-doped ZnO using triisopropyl borate as the boron precursor and comparison with Al-doped ZnO. J. Mater. Chem. C 2015, 3 (13), 3095-3107.

Lyu, S. C.; Han, J. H.; Shin, K. W.; Sok, J. H. Synthesis of boron-doped double-walled carbon nanotubes by the catalytic decomposition of tetrahydrofuran and triisopropyl borate. Carbon 2011, 49 (5), 1532-1541.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H225

Highly flammable liquid and vapour.

주의 설명서: P210-P280a-P240-P241-P303+P361+P353-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
1701469
위험 등급
3
포장 그룹
II
통합 관세 코드
2920.90
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
ED5950000

권장

최근에 본 것

화학물질

화학물질

금속 및 재료

촉매

분석 기기 및 실험실 용품