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838-57-3 - Ethyl 4-nitrobenzoylacetate, 97% - 4-Nitrobenzoylacetic acid ethyl ester - A17603 - Alfa Aesar

A17603 Ethyl 4-nitrobenzoylacetate, 97%

CAS 번호
838-57-3
동의어
4-Nitrobenzoylacetic acid ethyl ester

사이즈 가격 ($) 수량 재고 여부
10g 56.80
50g 248.00
250g 1031.00
장바구니에 추가 대량 견적에 추가 항목 보기

Ethyl 4-nitrobenzoylacetate, 97%

MDL
MFCD00007357
EINECS
212-656-7

화학적 특성

화학식
C11H11NO5
화학 식량
237.21
융점
68-73°

용도

It is employed as a reactant involved in synthesis of β-1,3-dicarbonyl aldehydes via oxidation, knoevenagel condensation using a lysine catalyst, and cycloisomerization for the synthesis of trisubstituted furans. It is also a reactant for the fluorination by HF and iodosylbenzene, intramolecular Michael addition reactions and synthesis of diols. Also applied in the synthesis of diols via reduction of aromatic and aliphatic ketos esters6 and cross-coupling reactions for stereo selective synthesis of unsymmetrical 1,4-enediones.

참고

Store away from oxidizing agents. Keep the container tightly closed in a cool, dry place.

참조 문헌

Weiping Liu.; Jinhua Liu.; Daisuke Ogawa.; Yasushi Nishihara.; Xingwei Guo.; Zhiping Li. Iron-catalyzed oxidation of tertiary amines: synthesis of β-1,3-dicarbonyl aldehydes by three-component C-C couplings.Org Lett.,2011,13(23), 6272-6275.

Tsugio Kitamura.; Satoshi Kuriki.; Mohammad Hasan Morshed.; Yuji Hori. A practical and convenient fluorination of 1,3-dicarbonyl compounds using aqueous HF in the presence of iodosylbenzene.Org Lett.2011,13(9), 2392-2394.

기타 참조

바일슈타인
1124763
통합 관세 코드
2918.30
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
AJ1073500

권장

최근에 본 것

화학물질

화학물질

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