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5437-45-6 - Benzyl bromoacetate, 97% - Bromoacetic acid benzyl ester - A17630 - Alfa Aesar

A17630 Benzyl bromoacetate, 97%

CAS 번호
5437-45-6
동의어
Bromoacetic acid benzyl ester

사이즈 가격 ($) 수량 재고 여부
50g 27.20
250g 93.40
1000g 286.00
장바구니에 추가 대량 견적에 추가 항목 보기

Benzyl bromoacetate, 97%

MDL
MFCD00000190
EINECS
226-611-4

화학적 특성

화학식
C6H5CH2CO2CH2Br
화학 식량
229.08
비등점
157-159°/10mm
인화점
>110°(230°F)
밀도
1.460
굴절률
1.5440
용해도
Not miscible or difficult to mix in water.

용도

It is employed in biological research purpose. Benzyl bromoacetate was used in the alkylation of (-)-2,3-O-isopropylidene-D-threitol that afforded lipopeptide, 2-[(4R,5R)-5-({[(9H-fluoren-9-yl)methoxy]carbonylaminomethyl}-2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]acetic acid.

참고

Store away from oxidizing agents and strong bases. Keep the container tightly closed in a cool, dry place. Store under 20?C Freezer, Under Inert Atmosphere.

참조 문헌

Herrin TR.; Fairgrieve JS.; Bower RR.; Shipkowitz NL. Synthesis and anti-herpes simplex activity of analogues of phosphonoacetic acid.J Med Chem.1977,20(5), 660-663.

Feagin TA.; Shah N.; Heemstra JM. Micellar. Convenient and scalable synthesis of fmoc-protected Peptide nucleic Acid backbone.J Nucleic Acids.2012,2012.

Toru Masaka.; Takuya Matsuda.; Yingpeng Li.; Yuki Koide.; Akira Takami.; Kenji Yano.; Ryosuke Imai.; Risa Ichihara.; Nobuhiro Yagi.; Hideharu Suzuki.; Hidemasa Hikawa.; Katsuhide Terada.; Yuusaku Yokoyama. Synthesis of VIP-lipopeptide using a new linker to modify liposomes: towards the development of a drug delivery system for active targeting.Chem Pharm Bull (Tokyo).2013,61(11), 1184-7.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

기타 참조

바일슈타인
973658
통합 관세 코드
2915.90
TSCA(독성물질규제법)"
No
RTECS(화학물질 독성 등록)
AF5957215

권장

  • A10605

    Methyl bromoacetate, 98+%
  • A11801

    N-Ethyldiisopropylamine, 99%
  • A12198

    Trifluoroacetic acid, 99%
  • A15682

    Benzyl chloroformate, 95%, stab. with ca 0.1% sodium carbonate
  • A16281

    Zinc chloride, anhydrous, 98+%

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