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Perfluorooctane may be used in chemical synthesis.
Cathrine Carlsen Bach.; Bodil Hammer Bech.; Nis Brix.; Ellen Aagaard Nohr.; Jens Peter Ellekilde Bonde.; Tine Brink Henriksen. Perfluoroalkyl and polyfluoroalkyl substances and human fetal growth: A systematic review.Crit Rev Toxicol.
Lo Nostro P and Chen SH. Aggregation of a semifluorinated n-alkane in perfluorooctane. J. Phys. Chem.,1993,97(24), 6535-40.
James E Klaunig.; Motoki Shinohara.; Hiroyuki Iwai.; Christopher P Chengelis.; Jeannie B Kirkpatrick.; Zemin Wang.; Richard H Bruner. Evaluation of the chronic toxicity and carcinogenicity of perfluorohexanoic acid (PFHxA) in Sprague-Dawley rats.Toxicol Pathol.,2015,43(2), 209-220.
Reaction medium with substantial capacity to solubilize molecular oxygen as in the photooxidation of alkenes: Synth. Commun., 26, 1861 (1996), or the high yield epoxidation of alkenes in the presence of trimethylacetaldehyde: Synth. Commun., 27, 447 (1997).