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1148-79-4 - 2,2':6',2''-Terpyridine, 97% - 2,6-Bis(2-pyridyl)pyridine - A17750 - Alfa Aesar

A17750 2,2':6',2''-Terpyridine, 97%

CAS 번호
1148-79-4
동의어
2,6-Bis(2-pyridyl)pyridine

사이즈 가격 ($) 수량 재고 여부
0.25g 44.80
1g 115.00
5g 388.00
장바구니에 추가 대량 견적에 추가 항목 보기

2,2':6',2''-Terpyridine, 97%

MDL
MFCD00006213
EINECS
214-559-5

화학적 특성

화학식
C15H11N3
화학 식량
233.28
융점
89-92°
용해도
Soluble in most organic solvents.

용도

2,2';6',2"-terpyridine is widely utilized in the field of supramolecular chemistry, which is used to manufacture the racks, ladders and grids, helicates, catenanes and dendrimers. It plays an important role as a ligand in coordination chemistry. Its complexes are employed in the oxidation of alcohols, the carbonylation of aromatic compounds and as oxygen-binding molecules. Functionalized terpyridine ligands were used in semiconductors and solar panels. It forms chealate complexes with europium(III) and terbium(III), which is used in protein labelling.

참고

Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

참조 문헌

Schönle, J.; Constable, E. C.; Housecroft, C. E.; Prescimone, A.; Zampese, J. E. Homoleptic and heteroleptic complexes of chromium(III) containing 4'-diphenylamino-2,2':6',2?-terpyridine ligands. Polyhedron 2015, 89 182-188.

Harper, B. W. J.; Aldrich-Wright, J. R. The synthesis, characterisation and cytotoxicity of bisintercalating (2,2':6',2''-terpyridine)platinum(II) complexes. Dalton Trans. 2015, 44 (1), 87-96.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H300-H310-H315-H319-H335

Fatal if swallowed. Fatal in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P261-P262-P301+P310a-P305+P351+P338-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

위험 등급
6.1
포장 그룹
I
통합 관세 코드
2933.39
TSCA(독성물질규제법)"
Yes

권장

  • L01190

    2,2'-Bipyrimidine, 96%
  • L14728

    4'-Chloro-2,2':6',2''-terpyridine, 98%
  • 11043

    Ruthenium(III) chloride hydrate, 99.9% (PGM basis), Ru 38% min
  • 11495

    Ammonium hexafluorophosphate, 99.5%
  • 30569

    2,2'-Bipyridine, ACS, 98%

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