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124-68-5 - 2-Amino-2-methyl-1-propanol, 95%, may cont. ca 5% water - AMP - Isobutanolamine - A17814 - Alfa Aesar

A17814 2-Amino-2-methyl-1-propanol, 95%, may cont. ca 5% water

CAS 번호
124-68-5
동의어
AMP
Isobutanolamine

사이즈 가격 ($) 수량 재고 여부
100ml 18.30
500ml 28.70
2500ml 92.60
장바구니에 추가 대량 견적에 추가 항목 보기

2-Amino-2-methyl-1-propanol, 95%, may cont. ca 5% water

MDL
MFCD00008051
EINECS
204-709-8

화학적 특성

화학식
C4H11NO
화학 식량
89.14
융점
24-28°
비등점
164-166°
인화점
67°(152°F)
밀도
0.934
굴절률
1.4455
용해도
Immiscible with water. Miscible with alcohols.

용도

2-Amino-2-methyl-1-propanol is used for the preparation of buffer solution and in cosmetics. It is also used in ATR-FTIR spectroscopic investigation of the carbon monoxide absorption characteristics of a series of heterocyclic diamines.

참고

Incompatible withoxidizing agents, strong acids, copper, brass and aluminum.

참조 문헌

Buffer and phosphate acceptor in assay of phosphatases: Methods of Enzymatic Analysis, 3rd ed., H. U. Bergmeyer, Ed., Verlag Chemie, Weinheim (1984), vol. 4, p76.

Precursor of 2-substituted-4,4-dimethyl-2-oxazoline derivatives of carboxylic acids: J. Org. Chem., 39, 2787 (1974), developed by Meyers. The oxazoline, which is readily formed with the acid chloride and thionyl chloride, is stable to base, organometallic reagents, etc., but readily cleaved by dilute acid. For further information on the reactivity of these derivatives, see 2,4,4-Trimethyl-2-oxazoline, L00181.

2-Aryl-4,4-dimethyl-2-oxazolines are activated towards ortho-lithiation: J. Org. Chem., 40, 3058 (1975). Methoxy- or fluoro-substituents in the ortho-position are readily substitutied by organolithiums or Grignards, providing a versatile route to biaryls: J. Am. Chem. Soc ., 97, 7383 (1975). For examples, see: Org. Synth. Coll., 9, 258 (1998). The oxazoline can also be converted to an aldehyde by methylation and borohydride reduction.

For reviews of the use of oxazolines in synthesis, see: Angew. Chem. Int. Ed., 15, 270 (1976); Tetrahedron, 41, 837 (1985); 50, 2297 (1994).

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Conway, W.; Bruggink, S.; Beyad, Y.; Luo, W.; Cabrera, I. M., Puxty, G.; Feron, P. CO2 absorption into aqueous amine blended solutions containing monoethanolamine (MEA), N, N-dimethylethanolamine (DMEA), N, N-diethylethanolamine (DEEA) and 2-amino-2-methyl-1-propanol (AMP) for post-combustion capture processes. Chem. Eng. Sci. 2015, 126, 446-454.

Halim, H. N. A.; Shariff, A. M.; Bustam, M. A. High pressure CO2 absorption from natural gas using piperazine promoted 2-amino-2-methyl-1-propanol in a packed absorption column. Sep. Purif. Technol. 2015, 152, 87-93.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H315-H319

Causes skin irritation. Causes serious eye irritation.

주의 설명서: P273-P280g-P305+P351+P338-P337+P313

Avoid release to the environment. Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.

기타 참조

Merck
14,449
바일슈타인
505979
통합 관세 코드
2922.19
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
UA5950000

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