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22445-41-6 - 5-Iodo-m-xylene, 97% - 1,3-Dimethyl-5-iodobenzene - 1-Iodo-3,5-dimethylbenzene - A18413 - Alfa Aesar

A18413 5-Iodo-m-xylene, 97%

CAS 번호
22445-41-6
동의어
1,3-Dimethyl-5-iodobenzene
1-Iodo-3,5-dimethylbenzene

사이즈 가격 ($) 수량 재고 여부
10g 42.40
50g 148.00
장바구니에 추가 대량 견적에 추가 항목 보기

5-Iodo-m-xylene, 97%

MDL
MFCD00060659
EINECS
000-000-0

화학적 특성

화학식
C8H9I
화학 식량
232.07
비등점
229°
인화점
>110°(230°F)
밀도
1.610
굴절률
1.5950
감도
Light Sensitive
용해도
Sparingly soluble (0.014 g/L) (25°C), Calc.

용도

1-Iodo-3,5-dimethylbenzene (5-iodo-m-xylene) is suitable for use in the synthesis of N-(3,5-xylyl)-N-ethyl aniline, an aryl amine, It is also used in the following studies; α-Arylation of ketones, Copper-catalyzed N-arylation of imidazoles, Cyanation of 5-iodo-m-xylene to form 3,5-dimethylbenzonitrile, synthesis of 1,3-Dimethyl-5-phenoxybenzene by nano-CuFe2O4 catalyzed C-O cross-coupling with phenol, CuBr-catalyzed amination of 1-iodo-3,5-dimethylbenzene to form N-Allyl-3,5-dimethylbenzenamine, copper-catalyzed C-S bond-formation between 5-iodo-m-xylene and thiophenol. It is also employed as a starting material in the synthesis of biphenyl-3,3’,5,5’-tetracarboxylic acid, radical bromination of 5-iodo-m-xylene by N-bromosuccinimide to form 1,3-bis(bromomethyl)-5-iodobenzene.

참고

Light Sensitive. Store away from oxidizing agents and light. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

참조 문헌

M H Ali.; S L Buchwald. An improved method for the palladium-catalyzed amination of aryl iodides. Org Chem.2001,66(8), 2560-2565.

Anouk S Lubbe, et. al. Control of rotor function in light-driven molecular motors.J. Org Chem.2011,76(21), 8599-8610.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

주의 설명서: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
2039353
통합 관세 코드
2903.99
TSCA(독성물질규제법)"
No

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