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693-13-0 - N,N'-Diisopropylcarbodiimide, 99% - DIC - A19292 - Alfa Aesar

A19292 N,N'-Diisopropylcarbodiimide, 99%

CAS 번호
693-13-0
동의어
DIC

사이즈 가격 ($) 수량 재고 여부
10g 25.50
25g 63.20
50g 108.00
250g 432.00
장바구니에 추가 대량 견적에 추가 항목 보기

N,N'-Diisopropylcarbodiimide, 99%

MDL
MFCD00065689
EINECS
211-743-7

화학적 특성

화학식
(CH3)2CHN=C=NCH(CH3)2
화학 식량
126.20
비등점
145-148°
인화점
33°(91°F)
밀도
0.810
굴절률
1.4330
감도
Moisture Sensitive
용해도
Soluble in chloroform, methylene chloride, acetonitrile, dioxane, dimethylformamide andtetrahydrofuran.

용도

N,N'-Diisopropylcarbodiimide is used as a reagent in synthetic organic chemistry. It serves as a chemical intermediate and as a stabilizer for Sarin (chemical weapon). It is also used in the synthesis of peptide and nucleic acid. Further, it is used as an antineoplastic and involved in the treatment of malignant melanoma and sarcomas. In addition to this, it is used in the synthesis of acid anhydride, aldehyde, ketone and isocyanate.

참고

Moisture sensitive. Store in a cool place Incompatible with oxidizing agents and acids.

참조 문헌

Reagent for peptide coupling: J. Org. Chem., 44, 5000 (1979). Has the advantage over N,N'-Dicyclohexyl­carbodiimide, A10973 in solid phase peptide syntheses that the urea by-product is more soluble in organic solvents and hence more readily separated from the polymer support. For peptide reagents, see Appendix 6.

Ogawa, T.; Usuki, N.; Nakazono, K.; Koyama, Y.; Takata, T. Linear-cyclic polymer structural transformation and its reversible control using a rational rotaxane strategy. Chem. Commun. 2015, 51 (26), 5606-5609.

Smith, J. M.; Moreno, J.; Boal, B. W.; Garg, N. K. Cascade Reactions: A Driving Force in Akuammiline Alkaloid Total Synthesis. Angew. Chem. Int. Ed. 2015, 54 (2), 400-412.

GHS 해저드 및 주의 설명서

해저드 설명서 (EU): H226-H330-H315-H318-H334-H317-H335

Flammable liquid and vapour. Fatal if inhaled. Causes skin irritation. Causes serious eye damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause respiratory irritation.

주의 설명서: P303+P361+P353-P304+P340-P305+P351+P338-P320-P405-P501a

IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

기타 참조

바일슈타인
878281
위험 등급
6.1
포장 그룹
II
통합 관세 코드
2925.19
TSCA(독성물질규제법)"
Yes
RTECS(화학물질 독성 등록)
FF2175000

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